Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
National Exams — May 2013 — 04-Chem-A1 Process Balances and Chemical Thermodynamics. Three-hour, open-book exam; any non-communicating calculator permitted. Format: seven questions in three parts — answer one of Q1–Q2 (Part A), one of Q3–Q4 (Part B) and two of Q5–Q7 (Part C); four questions of equal value constitute a complete paper. All seven are solved below for completeness. Where property data are needed they are stated explicitly in each Given block. Units follow the paper (mixed SI and US customary).
Reference texts: Felder, Rousseau & Bullard, Elementary Principles of Chemical Processes (4th ed., Wiley) — material & energy balances; Smith, Van Ness, Abbott & Swihart, Introduction to Chemical Engineering Thermodynamics (8th ed., McGraw-Hill) — VLE, residual properties, reaction equilibrium; supporting data from Perry's Chemical Engineers' Handbook (9th ed.) and the NIST Chemistry WebBook.