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23-Chem-A1 Process Balances and Chemical Thermodynamics: May 2013

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

  1. Question 1 Crystallization Separation of Sylvinite
  2. Question 2 Methanol Condensed in a Distillation Accumulator
  3. Question 3 Reactor with Recycle and Purge (Inert Build-up)
  4. Question 4 Coke Deposit in Propane Dehydrogenation
  5. Question 5 Heat Duty for Real-Gas Ethylene Heating
  6. Question 6 Bubble- and Dew-Point Pressures from the Margules Model
  7. Question 7 Synthesis-Gas Reaction Equilibria

Start with Question 1 →

National Exams — May 2013 — 04-Chem-A1 Process Balances and Chemical Thermodynamics. Three-hour, open-book exam; any non-communicating calculator permitted. Format: seven questions in three parts — answer one of Q1–Q2 (Part A), one of Q3–Q4 (Part B) and two of Q5–Q7 (Part C); four questions of equal value constitute a complete paper. All seven are solved below for completeness. Where property data are needed they are stated explicitly in each Given block. Units follow the paper (mixed SI and US customary).

Reference texts: Felder, Rousseau & Bullard, Elementary Principles of Chemical Processes (4th ed., Wiley) — material & energy balances; Smith, Van Ness, Abbott & Swihart, Introduction to Chemical Engineering Thermodynamics (8th ed., McGraw-Hill) — VLE, residual properties, reaction equilibrium; supporting data from Perry's Chemical Engineers' Handbook (9th ed.) and the NIST Chemistry WebBook.