23-Chem-A1 Process Balances and Chemical Thermodynamics · December 2017
Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
National Exams — December 2017 — 16-Chem-A1 Process Balances and Chemical Thermodynamics. Three-hour, open-book exam; any non-communicating calculator permitted. Format: two parts — Part A (Q1–Q3) Process Balances, Part B (Q4–Q6) Chemical Thermodynamics; the candidate answers two questions from each part (four constitute a complete paper, equal value). All six questions are solved below for completeness. Property data not printed on the paper (molar volumes at STP, gas constant, Rankine conversion) are stated explicitly in each Given block as open-book look-ups.
Reference texts: Felder, Rousseau & Bullard, Elementary Principles of Chemical Processes (4th ed., Wiley) — recycle balances, humidity and adiabatic-flame (energy) balances; Himmelblau & Riggs, Basic Principles and Calculations in Chemical Engineering (8th ed.) — multi-unit separation balances; Smith, Van Ness, Abbott & Swihart, Introduction to Chemical Engineering Thermodynamics (8th ed., McGraw-Hill) — cubic equations of state, residual properties, reaction/phase equilibrium and gas-cycle work; supporting property data from Perry’s Chemical Engineers’ Handbook (9th ed.).
Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.
Given. Wet solid enters at 15 wt% water and leaves at 7 wt% water. Air humidities (kg moisture per kg dry air): fresh $H_F=0.01$, recycle $H_R=0.10$, mixed air into the drier $H_M=0.03$. The recycle is drawn from the air leaving the drier, so exit-air humidity $=H_R=0.10$. Basis: 100 kg wet solid.
| Quantity | Value |
|---|---|
| Wet solid fed (basis) | 100 kg |
| — bone-dry solid (85%) | 85 kg |
| — water in feed (15%) | 15 kg |
| Product water content | 7 wt% |
| Fresh / mixed / recycle humidity | 0.01 / 0.03 / 0.10 |
Find. (a) water evaporated; (b) dry air in the fresh stream $F$; (c) dry air in the recycle stream $R$ — all per 100 kg wet solid.
Approach. A water balance on the solid fixes the evaporation; a humidity balance on the mixing tee relates $F$ and $R$; a moisture balance across the drier (dry air $F+R$ gains $H_M\!\to\!H_R$) closes the system.
Check: fresh air brings in $0.01(95.6)=0.96$ kg and recycle brings $0.10(27.3)=2.73$ kg into the tee, giving 3.69 kg on 122.9 kg dry air $=0.030$ — the specified mixed humidity, confirming closure.
| Quantity | Result (per 100 kg wet solid) |
|---|---|
| (a) Water evaporated | 8.60 kg |
| (b) Dry air in fresh stream | 95.6 kg |
| (c) Dry air in recycle stream | 27.3 kg |