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23-Chem-A1 Process Balances and Chemical Thermodynamics · December 2017

Question 1 of 6: Solids Drying with Air Recycle

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

National Exams — December 2017 — 16-Chem-A1 Process Balances and Chemical Thermodynamics. Three-hour, open-book exam; any non-communicating calculator permitted. Format: two parts — Part A (Q1–Q3) Process Balances, Part B (Q4–Q6) Chemical Thermodynamics; the candidate answers two questions from each part (four constitute a complete paper, equal value). All six questions are solved below for completeness. Property data not printed on the paper (molar volumes at STP, gas constant, Rankine conversion) are stated explicitly in each Given block as open-book look-ups.

Reference texts: Felder, Rousseau & Bullard, Elementary Principles of Chemical Processes (4th ed., Wiley) — recycle balances, humidity and adiabatic-flame (energy) balances; Himmelblau & Riggs, Basic Principles and Calculations in Chemical Engineering (8th ed.) — multi-unit separation balances; Smith, Van Ness, Abbott & Swihart, Introduction to Chemical Engineering Thermodynamics (8th ed., McGraw-Hill) — cubic equations of state, residual properties, reaction/phase equilibrium and gas-cycle work; supporting property data from Perry’s Chemical Engineers’ Handbook (9th ed.).

Question 1: Solids Drying with Air Recycle (Part A — equal value)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

Given. Wet solid enters at 15 wt% water and leaves at 7 wt% water. Air humidities (kg moisture per kg dry air): fresh $H_F=0.01$, recycle $H_R=0.10$, mixed air into the drier $H_M=0.03$. The recycle is drawn from the air leaving the drier, so exit-air humidity $=H_R=0.10$. Basis: 100 kg wet solid.

QuantityValue
Wet solid fed (basis)100 kg
— bone-dry solid (85%)85 kg
— water in feed (15%)15 kg
Product water content7 wt%
Fresh / mixed / recycle humidity0.01 / 0.03 / 0.10

Find. (a) water evaporated; (b) dry air in the fresh stream $F$; (c) dry air in the recycle stream $R$ — all per 100 kg wet solid.

MixingteeDrierSplitterFresh air FH=0.01Mixed airH=0.03Wet solid100 kg, 15% H2ODried solid7% H2OExit airH=0.10ExhaustRecycle R H=0.10
Figure 1 — Fresh air is blended with recycle at the mixing tee, passes through the drier picking up evaporated water, and the exit air is split into recycle and exhaust. The recycle and exhaust share the exit humidity of 0.10.

Approach. A water balance on the solid fixes the evaporation; a humidity balance on the mixing tee relates $F$ and $R$; a moisture balance across the drier (dry air $F+R$ gains $H_M\!\to\!H_R$) closes the system.

  1. Water removed from the solid (part a). The bone-dry solid (85 kg) is conserved. In the 7% product it is 93% of the mass, so the product $=85/0.93=91.40$ kg carrying $0.07\times91.40=6.40$ kg water. The evaporated water is the feed water minus the product water: $$w_{\text{evap}}=15-6.40=\boxed{8.60\ \text{kg water per 100 kg wet solid}}.$$
  2. Humidity balance on the mixing tee. Fresh dry air $F$ (at 0.01) and recycle dry air $R$ (at 0.10) blend to the mixed dry air $F+R$ at 0.03. Balancing moisture: $$0.01F+0.10R=0.03(F+R)\;\Rightarrow\;0.07R=0.02F\;\Rightarrow\;F=3.5\,R.$$ The tee alone fixes the fresh-to-recycle ratio without any reference to the drier.
  3. Moisture balance across the drier. The same dry air $(F+R)$ enters at 0.03 and leaves at 0.10, having absorbed the 8.60 kg of evaporated water: $$(F+R)(0.10-0.03)=8.60\;\Rightarrow\;F+R=\frac{8.60}{0.07}=122.9\ \text{kg dry air}.$$
  4. Solve for the two air streams (parts b, c). Substituting $F=3.5R$ into $F+R=4.5R=122.9$: $$R=\frac{122.9}{4.5}=\boxed{27.3\ \text{kg dry air (recycle)}},\qquad F=3.5R=\boxed{95.6\ \text{kg dry air (fresh)}}.$$

Check: fresh air brings in $0.01(95.6)=0.96$ kg and recycle brings $0.10(27.3)=2.73$ kg into the tee, giving 3.69 kg on 122.9 kg dry air $=0.030$ — the specified mixed humidity, confirming closure.

QuantityResult (per 100 kg wet solid)
(a) Water evaporated8.60 kg
(b) Dry air in fresh stream95.6 kg
(c) Dry air in recycle stream27.3 kg
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