23-Chem-A1 Process Balances and Chemical Thermodynamics · December 2018
Question 2 of 6: Cooling and Dehumidification of Humid Air
Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
Notes on this paper
Paper format. National Exam 16-Chem-A1, December 2018 — open-book, 3 hours. Two parts: Part A (Process Balances, Q1–Q3) and Part B (Chemical Thermodynamics, Q1–Q3). Candidates answer TWO from each part; each question is of equal value. All six questions are solved in full below.
Reference texts: Felder, Rousseau & Bullard, Elementary Principles of Chemical Processes (4th ed., Wiley) — degree-of-freedom analysis, separation trains, humidity and condensation energy balances, recycle systems; Himmelblau & Riggs, Basic Principles and Calculations in Chemical Engineering (8th ed.) — psychrometrics and recycle-ratio calculations; Smith, Van Ness, Abbott & Swihart, Introduction to Chemical Engineering Thermodynamics (8th ed., McGraw-Hill) — residual properties from a real-gas EOS, reaction equilibrium from ΔG°, and generalized/EOS fugacity coefficients; supporting critical-property data from Poling, Prausnitz & O’Connell, The Properties of Gases and Liquids (5th ed.).
Part A — Process Balances
Question A2: Cooling and Dehumidification of Humid Air (Part A — equal value)
Given. Moist air enters at $T_1=311$ K, $P=1$ atm, 97% relative humidity, at $\dot V=8.5$ m³/s (taken as the inlet volumetric flow). It leaves saturated at $T_2=291$ K. Property data as listed; $M_{H_2O}=18.02$ g/mol.
Quantity
Value
Inlet total molar flow $\dot n=P\dot V/RT_1$
333.1 mol/s
Inlet water mole fraction $y_w=0.97\,p^{sat}_1/P$
0.06344
Water in / dry air in
21.13 / 311.96 mol/s
Outlet humidity $Y_2=p^{sat}_2/(P-p^{sat}_2)$
0.02082 mol/mol dry
Find. (a) the water condensation rate in kg/min; (b) the total cooling duty expressed in tons of refrigeration.
Figure A2 — Humid air (311 K, 97% RH) is cooled to 291 K; the dry-air flow is conserved while the excess moisture drops out as liquid condensate and the exit air leaves saturated at 291 K.
Approach. Fix the conserved dry-air flow from the ideal-gas inlet state, set the exit vapour to saturation at 291 K, close a water balance for the condensate (part a), then evaluate an overall enthalpy balance using the stated dry-air correlation and steam-table water enthalpies (part b).
Inlet molar flow (ideal gas). At the inlet state,
$$\dot n=\frac{P\dot V}{RT_1}=\frac{(101{,}325)(8.5)}{(8.314)(311)}=333.1\ \text{mol/s}.$$
Split into water and dry air (Dalton). With $y_w=0.97\,p^{sat}_1/P=0.97(0.0654)=0.06344$,
$$\dot n_{w,\text{in}}=y_w\dot n=21.13\ \text{mol/s},\qquad \dot n_{\text{dry}}=\dot n-\dot n_{w,\text{in}}=311.96\ \text{mol/s}.$$
The dry-air flow is conserved through the cooler.
Exit water (saturation at 291 K). The leaving air is saturated, so its molar humidity is
$$Y_2=\frac{p^{sat}_2}{P-p^{sat}_2}=\frac{0.0204}{1-0.0204}=0.02082,\qquad \dot n_{w,\text{out}}=Y_2\,\dot n_{\text{dry}}=6.497\ \text{mol/s}.$$