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23-Chem-A1 Process Balances and Chemical Thermodynamics · December 2018

Question 2 of 6: Cooling and Dehumidification of Humid Air

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

Paper format. National Exam 16-Chem-A1, December 2018 — open-book, 3 hours. Two parts: Part A (Process Balances, Q1–Q3) and Part B (Chemical Thermodynamics, Q1–Q3). Candidates answer TWO from each part; each question is of equal value. All six questions are solved in full below.

Reference texts: Felder, Rousseau & Bullard, Elementary Principles of Chemical Processes (4th ed., Wiley) — degree-of-freedom analysis, separation trains, humidity and condensation energy balances, recycle systems; Himmelblau & Riggs, Basic Principles and Calculations in Chemical Engineering (8th ed.) — psychrometrics and recycle-ratio calculations; Smith, Van Ness, Abbott & Swihart, Introduction to Chemical Engineering Thermodynamics (8th ed., McGraw-Hill) — residual properties from a real-gas EOS, reaction equilibrium from ΔG°, and generalized/EOS fugacity coefficients; supporting critical-property data from Poling, Prausnitz & O’Connell, The Properties of Gases and Liquids (5th ed.).

Part A — Process Balances

Question A2: Cooling and Dehumidification of Humid Air (Part A — equal value)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

Given. Moist air enters at $T_1=311$ K, $P=1$ atm, 97% relative humidity, at $\dot V=8.5$ m³/s (taken as the inlet volumetric flow). It leaves saturated at $T_2=291$ K. Property data as listed; $M_{H_2O}=18.02$ g/mol.

QuantityValue
Inlet total molar flow $\dot n=P\dot V/RT_1$333.1 mol/s
Inlet water mole fraction $y_w=0.97\,p^{sat}_1/P$0.06344
Water in / dry air in21.13 / 311.96 mol/s
Outlet humidity $Y_2=p^{sat}_2/(P-p^{sat}_2)$0.02082 mol/mol dry

Find. (a) the water condensation rate in kg/min; (b) the total cooling duty expressed in tons of refrigeration.

Cooler311 -> 291 KHumid air in311 K, 97% RH, 8.5 m3/sCooled air out291 K, saturatedCondensate15.8 kg/min
Figure A2 — Humid air (311 K, 97% RH) is cooled to 291 K; the dry-air flow is conserved while the excess moisture drops out as liquid condensate and the exit air leaves saturated at 291 K.

Approach. Fix the conserved dry-air flow from the ideal-gas inlet state, set the exit vapour to saturation at 291 K, close a water balance for the condensate (part a), then evaluate an overall enthalpy balance using the stated dry-air correlation and steam-table water enthalpies (part b).

  1. Inlet molar flow (ideal gas). At the inlet state, $$\dot n=\frac{P\dot V}{RT_1}=\frac{(101{,}325)(8.5)}{(8.314)(311)}=333.1\ \text{mol/s}.$$
  2. Split into water and dry air (Dalton). With $y_w=0.97\,p^{sat}_1/P=0.97(0.0654)=0.06344$, $$\dot n_{w,\text{in}}=y_w\dot n=21.13\ \text{mol/s},\qquad \dot n_{\text{dry}}=\dot n-\dot n_{w,\text{in}}=311.96\ \text{mol/s}.$$ The dry-air flow is conserved through the cooler.
  3. Exit water (saturation at 291 K). The leaving air is saturated, so its molar humidity is $$Y_2=\frac{p^{sat}_2}{P-p^{sat}_2}=\frac{0.0204}{1-0.0204}=0.02082,\qquad \dot n_{w,\text{out}}=Y_2\,\dot n_{\text{dry}}=6.497\ \text{mol/s}.$$
  4. Condensate rate (water balance, part a). $$\dot n_{\text{cond}}=\dot n_{w,\text{in}}-\dot n_{w,\text{out}}=21.13-6.497=14.63\ \text{mol/s},$$ $$\dot m_{\text{cond}}=14.63\times0.01802\times60=\boxed{15.8\ \text{kg/min}}.$$
  5. Enthalpy inputs (part b). Using $H_{\text{dry}}=0.029(T_{{}^\circ\text{C}}-25)$ kJ/mol with $T_1=37.85\,{}^\circ\text{C}$, $T_2=17.85\,{}^\circ\text{C}$, and steam-table water enthalpies (kJ/kg × kg/s): $$\dot H_{\text{in}}=\dot n_{\text{dry}}(0.3727)+(\dot n_{w,\text{in}}M_w)(2570.8)=116.3+978.9=1095.2\ \text{kJ/s}.$$
  6. Enthalpy outputs and duty. The exit carries cooled dry air, saturated vapour, and the liquid condensate: $$\dot H_{\text{out}}=\dot n_{\text{dry}}(-0.2073)+(\dot n_{w,\text{out}}M_w)(2534.5)+(\dot n_{\text{cond}}M_w)(75.5)=-64.7+296.8+19.9=251.9\ \text{kJ/s}.$$ The heat removed is $\dot Q=\dot H_{\text{in}}-\dot H_{\text{out}}=843.2$ kJ/s $=3.036\times10^{6}$ kJ/hr, so $$\text{Cooling}=\frac{3.036\times10^{6}}{12{,}660}=\boxed{239.8\ \text{tons}}.$$
QuantityResult
Dry-air flow (conserved)311.96 mol/s
(a) Water condensed15.8 kg/min (14.63 mol/s)
Heat removed843.2 kJ/s
(b) Cooling requirement239.8 tons