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23-Chem-A3 Heat and Mass Transfer · December 2015

Question 3 of 7: Dimensional analysis of the spinning-disk mass-transfer coefficient

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

National Exams — December 2015 — 04-Chem-A3 (Mass Transfer Operations). Three-hour, open-book exam; any non-communicating calculator permitted. Format: seven questions in three parts — answer one of Q1–Q2 (Part A), one of Q3–Q4 (Part B) and two of Q5–Q7 (Part C); four questions of equal value constitute a complete paper. All seven are solved below for completeness. Every property datum (diffusivities, Henry’s constants, solubilities, packing constants) is supplied in the question or its data table, so each answer is self-contained.

Reference texts: Geankoplis, Transport Processes and Separation Process Principles (4th ed., Prentice Hall) — Knudsen/molecular diffusion, convective mass-transfer coefficients, gas absorption in packed towers; Welty, Wicks, Wilson & Rorrer, Fundamentals of Momentum, Heat and Mass Transfer (6th ed., Wiley) — boundary-layer analogies and dimensional analysis; Bird, Stewart & Lightfoot, Transport Phenomena (2nd ed., Wiley) — Chapman–Enskog kinetic theory; Treybal, Mass-Transfer Operations (3rd ed., McGraw-Hill) — Sherwood–Holloway packed-tower correlation; supporting data from Perry’s Chemical Engineers’ Handbook (9th ed.).

Question 3: Dimensional analysis of the spinning-disk mass-transfer coefficient (Part B — equal value)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

Given. A dimensional correlation for $k_c$ in terms of the three transport parameters $D_{AB}$, $\nu$ and $\omega$. There is no numerical data — the task is to non-dimensionalize a dimensional power law by introducing a characteristic length $L$ (the disk radius) that cancels out.

Find. Definitions of $Re$ and $Sc$, the non-dimensional group $Sh=A\,Re^{n}Sc^{m}$, and the constants $A$, $n$, $m$.

rotation axis ω (rad/s) soluble film on disk, radius L immersed in large stagnant fluid volume
Figure 3. Rotating soluble disk; the induced swirl provides the convective velocity scale $\omega L$ used to form $Re$.

Approach. Choose the natural velocity scale $u=\omega L$ and length scale $L$ (disk radius), form $Sh$, $Re$ and $Sc$, then substitute the given power law and confirm that $L$ cancels — forcing the exponents.

  1. (a) Dimensionless groups. With characteristic velocity $u=\omega L$, $$Re=\frac{uL}{\nu}=\frac{\omega L^2}{\nu},\qquad Sc=\frac{\nu}{D_{AB}},\qquad Sh=\frac{k_cL}{D_{AB}}.$$ The rotation supplies the velocity; $L$ is the disk radius.
  2. (b) Substitute the correlation. Insert $k_c=0.62\,D_{AB}^{2/3}\nu^{-1/6}\omega^{1/2}$ into $Sh=k_cL/D_{AB}$: $$Sh=0.62\,D_{AB}^{-1/3}\nu^{-1/6}\omega^{1/2}L.$$ Now write $$0.62\,Re^{1/2}Sc^{1/3}=0.62\left(\dfrac{\omega L^2}{\nu}\right)^{1/2}\left(\dfrac{\nu}{D_{AB}}\right)^{1/3}=0.62\,\omega^{1/2}L\,\nu^{-1/6}D_{AB}^{-1/3},$$ which is identical — $L$ appears to the first power on both sides and every exponent matches.
  3. (c) Constants. Therefore $$Sh=\boxed{0.62\,Re^{1/2}\,Sc^{1/3}},\qquad A=0.62,\ \ n=\tfrac12,\ \ m=\tfrac13.$$
QuantityResult
Reynolds number$Re=\omega L^2/\nu$
Schmidt number$Sc=\nu/D_{AB}$
Correlation$Sh=0.62\,Re^{1/2}Sc^{1/3}$
Constants$A=0.62,\ n=1/2,\ m=1/3$