23-Chem-A4 Chemical Reactor Engineering · December 2017
Question 2 of 5: Pulse-Tracer Analysis of a River — Tracer Quantity and Reach Volume
Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
Notes on this paper
Paper format. Chemical Engineering — 23-Chem-A4 Chemical Reactor Engineering, December 2017. Open-book, 3 hours. Five questions; answering any four constitutes a complete paper (each 25 marks). All five are solved below.
Reference texts. O. Levenspiel, Chemical Reaction Engineering, 3rd ed. (Wiley, 1999); H. S. Fogler, Elements of Chemical Reaction Engineering, 5th ed. (Pearson, 2016); Perry's Chemical Engineers' Handbook, 9th ed.
Question 2: Pulse-Tracer Analysis of a River — Tracer Quantity and Reach Volume (25 marks: a 18, b 7)
Given. Volumetric flow $Q = 6000\ \text{m}^3/\text{s}$; a triangular response curve $C(t)$ at the dam with $C=0$ for $t<20$ d, a linear rise to $C_{max}=10^{-6}$ units/m$^3$ at $t=35$ d, and a linear fall to $C=0$ at $t=125$ d. The half-life exceeds 10 years, so radioactive decay over the $\sim100$-day passage is negligible (the tracer is conserved).
Find. (a) total units of tracer injected; (b) volume of the river reach.
Approach. The dam records the exit-age (pulse) response, so the quantity injected is the flow times the area under $C(t)$ (zeroth moment), and the mean residence time is the centroid of $C(t)$ (first moment); the reach volume follows from $V = Q\bar t$.
Figure 2.1 — The measured triangular tracer pulse at the dam. Shaded area = ½(105 d)(10⁻⁶) fixes the injected quantity; the dashed line marks the centroid at t = 60 d, the mean residence time.
Conservation of the injected tracer (part a). Every unit dumped upstream must pass the dam (no decay), so $M = \displaystyle\int_0^\infty C\,Q\,dt = Q\!\int_0^\infty C\,dt = Q\,(\text{area under the }C\text{-}t\text{ curve}).$
Area of the triangular pulse. Base $= 125-20 = 105$ days, height $=10^{-6}$ units/m$^3$: $$\int C\,dt = \tfrac12 (105\ \text{d})(10^{-6}) = 52.5\times10^{-6}\ \tfrac{\text{units}\cdot\text{d}}{\text{m}^3}.$$
Convert to SI time and multiply by flow. With $1\ \text{d} = 86{,}400$ s, the area is $52.5\times10^{-6}\times86{,}400 = 4.536\ \text{units}\cdot\text{s}/\text{m}^3$, hence $$M = (6000)(4.536) = \boxed{2.72\times10^{4}\ \text{units}.}$$
Mean residence time (part b). For a pulse response, $\bar t = \dfrac{\int t\,C\,dt}{\int C\,dt}$, which is the time-centroid of the curve. The centroid of a triangle is the average of its three vertex times: $$\bar t = \frac{20 + 35 + 125}{3} = 60\ \text{days} = 5.184\times10^{6}\ \text{s}.$$