23-Chem-A6 Process Dynamics and Control · December 2018
Question 1 of 8: Stirred Tank with Thermal Solid — Model, Transfer Function, and Large-$UA$ Limit
Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
Notes on this paper
Reference texts: D. E. Seborg, T. F. Edgar, D. A. Mellichamp & F. J. Doyle III, Process Dynamics and Control (4th ed., Wiley) — Laplace-domain modelling, linearisation, transfer functions, feedback stability, frequency response and IMC design; G. Stephanopoulos, Chemical Process Control: An Introduction to Theory and Practice (Prentice Hall) — Routh test, Nyquist criterion, dead-time systems and state-space models; D. R. Coughanowr & S. E. LeBlanc, Process Systems Analysis and Control (3rd ed., McGraw-Hill) — first-order tank/thermal dynamics, step/impulse response and block-diagram algebra. Standard control conventions (deviation variables; unity valve/sensor gains unless stated) are used throughout. This sitting is an open-book paper of eight problems of which any five constitute a complete exam; all eight are solved here.
Problem 1: Stirred Tank with Thermal Solid — Model, Transfer Function, and Large-$UA$ Limit (20%)
Given. A jacket-free CSTR whose liquid exchanges heat with an internal solid of large heat capacity. (The printed text calls the inlet temperature $T_0$ while the exam figure labels the feed $T_a$; they are the same variable, written $T_a$ below.)
Quantity
Symbol
Role
Liquid thermal capacitance
$\rho V C_p$
energy storage in liquid
Solid thermal capacitance
$M C_m$
energy storage in solid
Flow capacity rate
$\rho F C_p$
convective in/out
Liquid–solid coupling
$UA$
heat transfer $UA(T-T_m)$
Input
$T_a(t)$
inlet temperature
Find. (a) the two coupled energy balances; (b) $\delta T(s)/\delta T_a(s)$; (c) the limiting behaviour as $UA\to\infty$.
Problem 1: liquid at $T$ exchanges heat with a solid slug at $T_m$ through $UA$; the two capacitances $\rho V C_p$ and $M C_m$ store energy in series, giving a second-order thermal response.
Approach. Write an energy balance on the liquid and a separate one on the solid (two states $T,T_m$), Laplace-transform in deviation variables, eliminate $T_m$, and read the limit by letting $UA$ dominate every term it appears in.
(a) Liquid energy balance. With constant $\rho,C_p$ and negligible losses, accumulation $=$ convection in $-$ convection out $-$ heat to solid: $$\rho V C_p\frac{dT}{dt}=\rho F C_p\,(T_a-T)-UA\,(T-T_m).$$
(a) Solid energy balance. The solid only exchanges with the liquid: $$M C_m\frac{dT_m}{dt}=UA\,(T-T_m).$$ These two coupled ODEs are the fundamental model; both variables start at steady state.
Deviation variables and Laplace. Let $a=\rho V C_p$, $b=\rho F C_p$, $c=M C_m$, and use $\delta$ for deviations. Transforming (initial deviations zero): $$a\,s\,\delta T=b(\delta T_a-\delta T)-UA(\delta T-\delta T_m),\qquad c\,s\,\delta T_m=UA(\delta T-\delta T_m).$$
Eliminate the solid state. From the solid equation $\displaystyle \delta T_m=\frac{UA}{c\,s+UA}\,\delta T$. Substituting and collecting $\delta T$, the coupling term becomes $UA-\dfrac{UA^2}{cs+UA}=\dfrac{UA\,c\,s}{cs+UA}$, so $$\Big[a\,s+b+\frac{UA\,c\,s}{c\,s+UA}\Big]\delta T=b\,\delta T_a.$$
(b) Transfer function. Multiplying through by $(cs+UA)$: $$\boxed{\frac{\delta T(s)}{\delta T_a(s)}=\frac{b\,(c\,s+UA)}{a c\,s^{2}+\big(a\,UA+c(b+UA)\big)s+b\,UA}.}$$ Setting $s=0$ gives a steady-state gain $bUA/bUA=1$ — at steady state the outlet fully follows the inlet, as it must with no other heat source. The system is second order (two capacitances in series) with a numerator zero at $s=-UA/c$.
(c) Limit $UA\to\infty$. Perfect coupling forces $T_m\to T$: the solid and liquid become one lumped mass. Keeping only the terms carrying $UA$ in the numerator and denominator, $$\frac{\delta T}{\delta T_a}\xrightarrow{UA\to\infty}\frac{bUA}{UA\big[(a+c)s+b\big]}=\frac{1}{\tau s+1},\qquad \boxed{\tau=\frac{a+c}{b}=\frac{\rho V C_p+M C_m}{\rho F C_p}.}$$ The two model equations in (a) merge into a single balance $(\rho V C_p+M C_m)\,dT/dt=\rho F C_p(T_a-T)$, and the second-order transfer function of (b) collapses to first order: the solid’s heat capacity simply adds to the liquid’s, and the numerator zero cancels.
Item
Result
(a) Liquid balance
$\rho V C_p\,\dot T=\rho F C_p(T_a-T)-UA(T-T_m)$
(a) Solid balance
$M C_m\,\dot T_m=UA(T-T_m)$
(b) $\delta T/\delta T_a$
$\dfrac{b(cs+UA)}{acs^2+(aUA+c(b+UA))s+bUA}$, gain $=1$
(c) $UA\to\infty$
first order, $\tau=(\rho V C_p+M C_m)/(\rho F C_p)$