Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
Notes on this paper
National Exam 04-Chem-B10, Life Cycle Assessment (LCA) — December 2013. 3 hours, Closed-Book
Exam (Casio/Sharp approved calculator and one double-sided aid sheet permitted). Question 1 is
mandatory; any three (3) of the remaining four (Questions 2–5) constitute a complete 100-mark
paper, and only the first four questions as they appear in the answer book are marked. All five
questions (and, in Question 5, all five sub-parts) are solved below for completeness.
Reference texts: Baumann & Tillman, The Hitch Hiker's Guide to LCA;
Graedel & Allenby, Industrial Ecology and Sustainable Engineering; Kemp, Pinch
Analysis and Process Integration, 2nd ed.; Mackay, Multimedia Environmental Models: The
Fugacity Approach, 2nd ed.; Davis & Cornwell, Introduction to Environmental
Engineering.
Find. (a) Utility type and flow rate per stream with no integration. (b) Pinch
temperature and minimum hot/cold utility duties via the problem-table (temperature-interval) method.
(c) A feasible heat exchanger network achieving those minimum utility targets.
Approach. Compute each stream's duty CP·ΔT; without integration each
stream is served by whichever utility is both hot/cold enough and cheapest, sized by Q = ẓ·ΔH.
With integration, shift hot streams down and cold streams up by ΔTmin/2, tabulate the
net CP imbalance in each temperature interval between consecutive shifted stream temperatures, cascade
the heat downward from zero at the top, and add the minimum heat needed at the top to make every
cascade value ≥0 — the point where the cascade first reaches exactly zero is the pinch. A
network is then built stream-by-stream honouring the pinch-matching feasibility rule (CPhot
≤ CPcold for any match touching the pinch from above).
(a) Utility duties without heat integration. Each stream's total duty:
$$Q_{C101}=32.0\times(165-105)=1920\ \text{kW},\quad Q_{H102}=20.0\times(185-50)=2700\ \text{kW},\quad
Q_{C103}=22.5\times(120-50)=1575\ \text{kW}$$
C101's target (165°C) exceeds the practical ceiling of LPS (≈160°C condensing — too
close to 165°C to leave a 10°C approach), so it must be served by HPS; C103's
target (120°C) is comfortably below LPS's ceiling, so the cheaper LPS serves it;
H102 needs only sensible cooling well within the CW range, so CW serves it. Sizing each
from Q = ẓ·|ΔH|:
$$\dot m_{HPS}=\frac{1920}{1700}=\boxed{1.129\ \text{kg/s}},\qquad
\dot m_{LPS}=\frac{1575}{2000}=\boxed{0.788\ \text{kg/s}},\qquad
\dot m_{CW}=\frac{2700}{63}=\boxed{42.86\ \text{kg/s}}$$
(b) Shifted temperatures and the problem-table cascade. Shift cold streams up
5°C and the hot stream down 5°C (half of ΔTmin) onto a common scale:
C101*: 110→170°C; H102*: 180→45°C; C103*: 55→125°C. The six distinct shifted
temperatures (180, 170, 125, 110, 55, 45) bound five intervals; in each interval, net
= (ΣCPhot − ΣCPcold)×ΔT of the streams spanning it:
$$[180,170]:\ (20-0)(10)=+200 \quad [170,125]:\ (20-32)(45)=-540 \quad [125,110]:\ (20-54.5)(15)=-517.5$$
$$[110,55]:\ (20-22.5)(55)=-137.5 \quad [55,45]:\ (20-0)(10)=+200$$
Cascading from Q=0 at the top gives running totals 0, 200, −340, −857.5, −995,
−795 — the most negative value is −995 kW, so adding
QH,min = 995 kW at the top makes every value ≥0. The re-cascaded values are
995, 1195, 655, 137.5, 0, 200 — the cascade hits exactly zero at shifted T*=55°C,
which is the pinch (actual hot-stream pinch temperature 60°C, actual cold-stream pinch temperature
50°C), and the final value, QC,min = 200 kW, is the minimum cold utility.
$$Q_{H,min}=\boxed{995\ \text{kW (above pinch)}}\qquad Q_{C,min}=\boxed{200\ \text{kW (below pinch)}}$$
Energy-balance check. Total process heating demand minus total cooling demand
(1920+1575−2700 = 795 kW) must equal QH,min−QC,min = 995−200 =
795 kW — confirmed. Heat integration recovers 2500 kW of process-to-process exchange (versus
3495+2700 = 6195 kW of total utility duty with no integration at all), an 80.7% reduction in total
utility load.
Fig. 1 — Temperature-interval (problem-table) cascade. The cascade first
touches zero at shifted T*=55°C (actual pinch 60°C hot / 50°C cold), fixing
QH,min=995 kW and QC,min=200 kW.
(c) Heat exchanger network design. Above the pinch there is one hot stream (H102,
CP=20) and two cold streams (C101, CP=32; C103, CP=22.5); since CPhot ≤ CPcold
for either pairing, a match at the pinch is feasible with either. Take the pinch match as H102/C103
(the pinch-design "tick-off" heuristic): running H102 from the pinch (60°C) up while heating C103
fully from 50 to 120°C uses
$$Q_{E2}=22.5\times(120-50)=1575\ \text{kW}\ \Rightarrow\ H102: 138.75^\circ\text{C}\rightarrow60^\circ\text{C}$$
which fully satisfies C103 (no utility needed for this stream) and is feasible throughout (10°C
approach at the pinch end, 18.75°C at the top end — both ≥ΔTmin). The
remaining H102 capacity above the pinch (185→138.75°C) is then matched against the cold end of
C101:
$$Q_{E1}=20\times(185-138.75)=925\ \text{kW}\ \Rightarrow\ C101: 105^\circ\text{C}\rightarrow133.9^\circ\text{C}$$
(feasible: 33.75°C approach at the cold end, 51.1°C at the hot end). C101's remaining duty up to
its 165°C target,
$$Q_{E3}=1920-925=\boxed{995\ \text{kW}}=Q_{H,min},$$
must be supplied by HPS, since the 165°C target is beyond LPS's reach — confirming the same
QH,min found by the cascade. Below the pinch, only H102 remains (60→50°C), cooled by
CW:
$$Q_{E4}=20\times(60-50)=\boxed{200\ \text{kW}}=Q_{C,min}$$
Utility flow rates for the integrated network: $\dot m_{HPS}=995/1700=\boxed{0.585\ \text{kg/s}}$,
$\dot m_{CW}=200/63=\boxed{3.17\ \text{kg/s}}$. This 4-exchanger network (E1, E2, E3-heater, E4-cooler)
matches the minimum-units target, Nunits = Nstreams − 1 on each side of the pinch (above: H102, C101, C103, HPS ⇒ 3 units; below: H102, CW ⇒ 1 unit), and achieves both minimum utility targets exactly.
Fig. 2 — Grid diagram of the integrated heat exchanger network. H102 (top,
flowing right) is cooled sequentially by E1 (against C101) then E2 (the pinch match, against C103,
green), both above the pinch, then by the CW cooler E4 below it; the cold streams flow counter-current
(right to left), and C101 finishes in the HPS heater E3 above the pinch.