Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
Notes on this paper
National Exam 16-Chem-B10, Life Cycle Assessment (LCA) — December 2018. 3 hours, Closed-Book
Exam (approved calculator and one double-sided aid sheet permitted). Question 1 is mandatory (28
marks); any three (3) of the remaining four (Questions 2–5) constitute a complete 100-mark paper,
and only the first four questions as they appear in the answer book are marked. All five questions are
solved below for completeness.
Reference texts: Baumann & Tillman, The Hitch Hiker's Guide to LCA;
Graedel & Allenby, Industrial Ecology and Sustainable Engineering; Kemp, Pinch
Analysis and Process Integration, 2nd ed.; Mackay, Multimedia Environmental Models: The
Fugacity Approach, 2nd ed.; Davis & Cornwell, Introduction to Environmental
Engineering.
Find. (a) Utility type and flow rate per stream with no integration. (b) Pinch
temperature and minimum hot/cold utility duties via the problem-table (temperature-interval) method.
(c) A feasible heat exchanger network achieving those minimum utility targets.
Approach. Compute each stream's duty CP·ΔT; without integration each
stream is served by whichever utility is both hot/cold enough and cheapest, sized by Q =
ẓ·ΔH. With integration, shift hot streams down and cold streams up by
ΔTmin/2, tabulate the net CP imbalance in each temperature interval between consecutive
shifted stream temperatures, cascade the heat downward from zero at the top, and add the minimum heat
needed at the top to make every cascade value ≥0 — the point where the cascade first reaches
exactly zero is the pinch. A network is then built stream-by-stream honouring the pinch-matching
feasibility rule (CPhot ≤ CPcold for any match touching the pinch from above).
(a) Utility duties without heat integration. Each stream's total duty:
$$Q_{H101}=33.0\times(190-50)=4620\ \text{kW},\quad Q_{C102}=48.0\times(175-85)=4320\ \text{kW},\quad
Q_{C103}=20.0\times(115-50)=1300\ \text{kW}$$
C102's target (175°C) requires a utility temperature of at least 175+10=185°C to hold a 10°C
approach, which LPS ($\approx$160°C condensing) cannot supply, so C102 must be served by
HPS; C103's target (115°C) needs only $\ge$125°C, comfortably below LPS's
ceiling, so the cheaper LPS serves it; H101 needs only sensible cooling well within the
CW range, so CW serves it. Sizing each from ẓ = Q/|ΔH|:
$$\dot m_{HPS}=\frac{4320}{1700}=\boxed{2.541\ \text{kg/s}},\qquad
\dot m_{LPS}=\frac{1300}{2000}=\boxed{0.650\ \text{kg/s}},\qquad
\dot m_{CW}=\frac{4620}{63}=\boxed{73.33\ \text{kg/s}}$$
(b) Shifted temperatures and the problem-table cascade. Shift the hot stream down
5°C and the cold streams up 5°C (half of ΔTmin) onto a common scale: H101*:
185→45°C; C102*: 90→180°C; C103*: 55→120°C. The six distinct shifted
temperatures (185, 180, 120, 90, 55, 45) bound five internal intervals; in each interval, net =
(ΣCPhot − ΣCPcold)×ΔT of the streams spanning it:
$$[185,180]:\ (33-0)(5)=+165 \quad [180,120]:\ (33-48)(60)=-900 \quad [120,90]:\ (33-48-20)(30)=-1050$$
$$[90,55]:\ (33-20)(35)=+455 \quad [55,45]:\ (33-0)(10)=+330$$
Cascading from Q=0 at the top gives running totals 0, 165, −735, −1785, −1330,
−1000 — the most negative value is −1785 kW, so adding QH,min = 1785
kW at the top makes every value ≥0. The re-cascaded values are 1785, 1950, 1050,
0, 455, 785 — the cascade hits exactly zero at shifted T*=90°C, which is the
pinch (actual hot-stream pinch temperature 95°C, actual cold-stream pinch temperature 85°C), and
the final value, QC,min = 785 kW, is the minimum cold utility.
$$Q_{H,min}=\boxed{1785\ \text{kW (above pinch)}}\qquad Q_{C,min}=\boxed{785\ \text{kW (below pinch)}}$$
Energy-balance check. Total process heating demand minus total cooling demand
(4320+1300−4620 = 1000 kW) must equal QH,min−QC,min =
1785−785 = 1000 kW — confirmed. Heat integration recovers 3735 kW of process-to-process
exchange (versus 5620+4620 = 10,240 kW of total utility duty with no integration at all), a 74.5%
reduction in total utility load.
Fig. 1 — Temperature-interval (problem-table) cascade. The cascade first
touches zero at shifted T*=90°C (actual pinch 95°C hot / 85°C cold), fixing
QH,min=1785 kW and QC,min=785 kW.
(c) Heat exchanger network design. Above the pinch there is one hot stream (H101,
CP=33) and two cold streams (C102, CP=48; C103, CP=20); since Nhot
(1) ≤ Ncold (2) above the pinch, no stream split is required. Checking the pinch-matching
feasibility rule (CPhot≤CPcold for any match touching the pinch), H101
(CP=33) can only be matched against C102 (CP=48≥33) at the pinch — matching directly against
C103 (CP=20<33) would violate the rule and cause the approach temperature to shrink below 10°C
moving away from the pinch. C102's cold inlet (85°C) sits exactly at the cold-pinch temperature, so
E1 is the pinch match: running H101 the full length of its above-pinch range
(95→190°C) into C102 transfers
$$Q_{E1}=33\times(190-95)=\boxed{3135\ \text{kW}}\ \Rightarrow\ C102: 85^\circ\text{C}\rightarrow\left(85+\frac{3135}{48}\right)=150.3^\circ\text{C}$$
(feasible: 10°C approach at the pinch end, 39.7°C at the hot end). C102's remaining duty up to
its 175°C target,
$$Q_{E2}=4320-3135=\boxed{1185\ \text{kW}}=Q_{H,min}-Q_{E3},$$
must be supplied by HPS (1185/1700 = 0.697 kg/s), since 175°C is beyond LPS's
reach. C103 (85→115°C, CP=20) is not touched by H101 at all (H101 is fully committed to C102
above the pinch), so it is heated entirely by LPS:
$$Q_{E3}=20\times(115-85)=\boxed{600\ \text{kW}}\qquad(0.300\ \text{kg/s LPS})$$
confirming $Q_{E2}+Q_{E3}=1185+600=1785\ \text{kW}=Q_{H,min}$. Below the pinch, only H101 (CP=33) and
C103's below-pinch segment (50→85°C, CP=20) remain (Ncold=1≤Nhot=1,
CPhot≥CPcold as required below the pinch), forming the second process match,
E4:
$$Q_{E4}=20\times(85-50)=\boxed{700\ \text{kW}}\ \Rightarrow\ H101: 95^\circ\text{C}\rightarrow\left(95-\frac{700}{33}\right)=73.8^\circ\text{C}$$
(feasible: 10°C approach at the pinch end, 23.8°C at the cold end). H101's remaining duty down
to its 50°C target,
$$Q_{E5}=33\times(73.8-50)=\boxed{785\ \text{kW}}=Q_{C,min},$$
is removed by CW (785/63 = 12.46 kg/s), confirming the below-pinch target. This
5-exchanger network (E1, E2-heater, E3-heater, E4, E5-cooler) achieves both minimum utility targets
exactly, with no stream split anywhere in the design.
Fig. 2 — Grid diagram of the integrated heat exchanger network. H101 (top,
flowing left to right) is cooled by E1 (against C102, the above-pinch match) then continues through the
pinch to E4 (against C103's below-pinch segment) before a CW trim cooler E5; C102 finishes against an
HPS heater E2 above the pinch, and C103 is heated entirely by an LPS heater E3.