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23-Chem-B8 Polymer Engineering · December 2014

Question 5 of 7: Creep of a standard-linear-solid model (Kelvin–Voigt in series with a spring)

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

National Exam 04-Chem-B8, Polymer Engineering — December 2014. Three hours, OPEN BOOK (any non-communicating calculator). The paper is in four parts: Part A (Q1–2, 20 marks each), Part B (Q3–4, 30 marks each), Part C (Q5–6, 30 marks each) and Part D (Q7, 20 marks). A candidate answers ONE question from each of A, B, C and the single question in D — four questions constitute a complete paper. For completeness this solution works all seven questions in full.

Reference texts: Rudin & Choi, The Elements of Polymer Science and Engineering, 3rd ed.; Sperling, Introduction to Physical Polymer Science, 4th ed.; Odian, Principles of Polymerization, 4th ed.; Young & Lovell, Introduction to Polymers, 3rd ed.; Painter & Coleman, Fundamentals of Polymer Science, 2nd ed.

Question 5: Creep of a standard-linear-solid model (Kelvin–Voigt in series with a spring) (Part C — 30 marks)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

Given. Series combination of a Kelvin–Voigt element (\(E_1\parallel\eta_1\)) and a lone spring \(E_2\), under constant stress \(\sigma\). Measured strains: \(\epsilon(0^+)=0.002\), \(\epsilon(1000\,\text{s})=0.004\), \(\epsilon(\infty)=0.006\).

Find. (a) \(\epsilon(t)\); (b) the retardation time \(\tau_1\); (c) the creep–recovery curve.

E₁ (spring) η₁ (dashpot) E₂ (spring) Kelvin–Voigt element σ
Mechanical analogue: a lone spring \(E_2\) in series with a Kelvin–Voigt element (\(E_1\) parallel to dashpot \(\eta_1\)). The series spring gives the instantaneous jump; the Kelvin element gives the delayed, fully-recoverable creep.

Approach. Add the strains of series elements: the lone spring responds instantly, the Kelvin element responds with a delayed exponential of time constant \(\tau_1=\eta_1/E_1\); pin the two compliances and \(\tau_1\) from the three data points.

(a) Total-strain expression

Elements in series carry the same stress \(\sigma\) and their strains add. The lone spring gives an instantaneous elastic strain \(\sigma/E_2\); the Kelvin–Voigt element under constant stress creeps as \((\sigma/E_1)(1-e^{-t/\tau_1})\). Therefore

\(\displaystyle \boxed{\;\epsilon(t)=\frac{\sigma}{E_2} +\frac{\sigma}{E_1}\left(1-e^{-t/\tau_1}\right),\qquad \tau_1=\frac{\eta_1}{E_1}. }\)

(b) Retardation time

  1. Instantaneous response fixes \(\sigma/E_2\). At \(t=0^+\) the Kelvin term is zero, so \(\epsilon(0^+)=\sigma/E_2=0.002\).
  2. Long-time plateau fixes \(\sigma/E_1\). As \(t\to\infty\) the exponential dies and \(\epsilon(\infty)=\sigma/E_2+\sigma/E_1=0.006\), hence \(\sigma/E_1=0.006-0.002=0.004\).
  3. Intermediate point fixes \(\tau_1\). At \(t=1000\) s, $$0.004 = 0.002+0.004\left(1-e^{-1000/\tau_1}\right) \;\Rightarrow\; 1-e^{-1000/\tau_1}=0.5 \;\Rightarrow\; e^{-1000/\tau_1}=0.5.$$ Thus \(1000/\tau_1=\ln 2\) and $$\tau_1=\frac{1000}{\ln 2}=\boxed{1443\ \text{s}}.$$

(c) Creep and recovery

0.0000 0.0014 0.0027 0.0041 0.0054 0.0068 t=1000 s (unload) 0.002 (instant, σ/E₂) 0.004 @1000 s ε∞ = 0.006 (σ/E₂+σ/E₁) creep recovery → 0 time t (s) strain ε
Creep–recovery response. On loading: an instantaneous jump to \(\sigma/E_2=0.002\), then delayed creep toward \(\epsilon_\infty=0.006\), passing through 0.004 at 1000 s. On unloading at 1000 s: an instantaneous elastic recovery of \(\sigma/E_2=0.002\) (drop to 0.002), then the Kelvin strain decays exponentially with the same \(\tau_1\) to zero permanent set.

Because there is no free (series) dashpot, all of the strain is recoverable: the series spring recovers instantly and the Kelvin element relaxes back to zero, leaving no permanent set. At the moment of unloading the Kelvin strain is \(\epsilon_K(1000)=0.004(1-e^{-\ln2})=0.002\); it then decays as \(0.002\,e^{-(t-1000)/\tau_1}\).

QuantityValue
Instantaneous compliance \(\sigma/E_2\)0.002
Delayed (Kelvin) compliance \(\sigma/E_1\)0.004
Retardation time \(\tau_1=\eta_1/E_1\)1443 s (\(=1000/\ln2\))
Permanent set after recovery0 (fully recoverable)