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23-Chem-B8 Polymer Engineering · May 2016

Question 2 of 6: Two-Layer Tube Flow — Newtonian Core and Power-Law Annulus

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

Paper format: Open-book, 3 hours; six numbered problems of equal value (20 marks each), of which five constitute a complete paper (only the first five in the answer book are marked). All six problems are solved below so the set is complete for study.

Reference texts: Odian, Principles of Polymerization (4th ed., Wiley) — chain- and step-growth kinetics, emulsion polymerization, molecular-weight distributions; Rudin & Choi, The Elements of Polymer Science and Engineering (3rd ed., Academic Press) — dilute-solution properties, osmometry, viscoelasticity; Sperling, Introduction to Physical Polymer Science (4th ed., Wiley) — linear viscoelasticity, terminal-zone moduli; Bird, Armstrong & Hassager, Dynamics of Polymeric Liquids, Vol. 1 — non-Newtonian tube flow; supporting polyolefin process detail from Young & Lovell, Introduction to Polymers (3rd ed.).

Question 2: Two-Layer Tube Flow — Newtonian Core and Power-Law Annulus (20 marks)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

Given.

QuantitySymbolValue
Interface (core) radiusR14 mm = 0.004 m
Wall radiusR25 mm = 0.005 m
Newtonian viscosity of AμA10 Pa·s
Consistency of Bm10 Pa·sn
Power-law index of Bn0.5
Pressure gradientG = −dP/dz5×104 Pa·m-1

Find. (a) umax (centreline); (b) u at r = R1; (c) Q = QA + QB.

Approach. A momentum balance on a thin cylindrical fluid element fixes the shear stress $\tau_{rz}=\tfrac12 G r$ everywhere in the tube regardless of the constitutive law, so stress continuity across the interface is automatic; integrating each fluid's rate-of-strain from the wall inward, using velocity continuity at R1, gives the two velocity profiles and their integrals.

Check

The datum "zero-shear viscosity of B = 10 Pa·s" is read as the power-law consistency m = 10 Pa·sn (a true zero-shear viscosity is undefined for a shear-thinning power law, which diverges as γ̇→0). "i0 Pa.s" for A is read as 10 Pa·s.

  1. Shear-stress distribution. For steady, fully-developed axial flow a momentum balance on a thin cylindrical fluid element gives, in both regions, $$\tau_{rz}(r)=\frac{G\,r}{2},\qquad G=-\frac{dP}{dz}=5\times10^{4}\ \text{Pa}\cdot\text{m}^{-1}$$ so the stress is continuous at R1 by construction.
  2. Annulus B (power-law), integrate from the wall. With $\tau=m|du/dr|^{n}$ and $du/dr<0$, $-du/dr=(Gr/2m)^{1/n}$. Integrating from R2 (u = 0) inward: $$u_B(r)=\left(\frac{G}{2m}\right)^{1/n}\frac{n}{n+1}\left[R_2^{\frac{n+1}{n}}-r^{\frac{n+1}{n}}\right]$$ With n = 0.5 the exponents are 1/n = 2 and (n+1)/n = 3, and $(G/2m)^{2}=(2500)^2=6.25\times10^{6}$.
  3. (b) Interface velocity at r = R1: $$u_B(R_1)=\frac{6.25\times10^{6}}{3}\left[(0.005)^3-(0.004)^3\right]=2.083\times10^{6}\times6.1\times10^{-8}=\boxed{0.127\ \text{m}\cdot\text{s}^{-1}}$$
  4. Core A (Newtonian), integrate from the interface. With $\tau=\mu_A(-du/dr)$, $-du/dr=Gr/2\mu_A$; integrating inward from R1 with velocity continuity $u_A(R_1)=u_B(R_1)$: $$u_A(r)=u_B(R_1)+\frac{G}{4\mu_A}\left(R_1^2-r^2\right)$$
  5. (a) Maximum velocity at the centreline r = 0, where $G/4\mu_A=1250$: $$u_{max}=0.127+1250\,(0.004)^2=0.127+0.020=\boxed{0.147\ \text{m}\cdot\text{s}^{-1}}$$
  6. (c) Volumetric flow rates, $Q=\int u\,2\pi r\,dr$ over each region: $$Q_A=2\pi\!\left[\frac{u_B(R_1)R_1^2}{2}+\frac{G R_1^4}{16\mu_A}\right]=6.89\times10^{-6}\ \text{m}^3\text{s}^{-1}$$ $$Q_B=2\pi\!\left(\frac{G}{2m}\right)^{1/n}\!\frac{n}{n+1}\!\left[\frac{R_2^{3}(R_2^2-R_1^2)}{2}-\frac{R_2^{5}-R_1^{5}}{5}\right]=1.86\times10^{-6}\ \text{m}^3\text{s}^{-1}$$ $$Q=Q_A+Q_B=\boxed{8.75\times10^{-6}\ \text{m}^3\text{s}^{-1}=8.75\ \text{cm}^3\text{s}^{-1}}$$
radial position r (mm)axial velocity u (m/s)Two-layer velocity profile (core A + annulus B)0.0000.0290.0590.0880.1180.147012345interfacecore A (Newtonian)annulus B (power-law)u_max=0.147u_int=0.127
Fig. 2 — axial velocity profile: parabolic Newtonian core (0–4 mm) joined with velocity continuity to the shear-thinning power-law annulus (4–5 mm), whose profile is flatter than a Newtonian annulus would be at the same wall stress; centreline umax = 0.147 m/s, interface u = 0.127 m/s.
QuantityValue
(a) Maximum (centreline) velocity0.147 m·s-1
(b) Interface velocity (r = 4 mm)0.127 m·s-1
Core flow rate, QA6.89×10-6 m³/s
Annulus flow rate, QB1.86×10-6 m³/s
(c) Total flow rate, Q8.75×10-6 m³/s (8.75 cm³/s)