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23-Chem-B8 Polymer Engineering · May 2017

Question 5 of 6: Injection of a Power-Law Melt into a Runner

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

Paper format: Open-book, 3 hours; six numbered problems of equal value (20 points each), of which five constitute a complete paper (only the first five in the answer book are marked). All six problems are solved below so the set is complete for study.

Reference texts: Odian, Principles of Polymerization (4th ed., Wiley) — chain-growth & living/anionic kinetics, molecular-weight distributions; Rudin & Choi, The Elements of Polymer Science and Engineering (3rd ed., Academic Press) — dilute-solution rheology, MWD averages, capillary viscometry; Tadmor & Gogos, Principles of Polymer Processing (2nd ed., Wiley) — calendering, injection filling, die flow; Sperling, Introduction to Physical Polymer Science (4th ed., Wiley) — viscoelasticity; Young & Lovell, Introduction to Polymers (3rd ed.) — polyolefin processing; Middleman, Fundamentals of Polymer Processing — power-law tube/runner flow.

Question 5: Injection of a Power-Law Melt into a Runner (20 points: 15 + 5)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

Given.

QuantitySymbolValue
Consistencym2.18×104 N·sn/m2
Power-law indexn0.39
Volumetric injection rateQ1.2×10-6 m3/s
Runner lengthL0.254 m
Runner radiusR2.54×10-3 m

Find. (a) ΔP(t) and penetration depth z(t); (b) the pressure to fill the full runner.

Approach. Constant Q fixes the melt-front position linearly in time; the power-law tube-flow law gives the pressure drop over the currently-filled length, so pressure rises linearly with penetration and hence with time.

  1. Penetration depth. A constant volumetric rate fills a constant cross-section, so the melt front advances at a fixed speed:$$z(t)=\frac{Q\,t}{\pi R^2}=\frac{1.2\times10^{-6}}{\pi(2.54\times10^{-3})^2}\,t=\boxed{0.0592\,t\ \text{m}}\quad(t\ \text{in s})$$
  2. Power-law pressure gradient. For a power-law fluid in a tube the throughput and pressure drop over a filled length z are related by $Q=\dfrac{\pi n R^3}{3n+1}\left(\dfrac{R\,\Delta P}{2mz}\right)^{1/n}$; solving for the gradient,$$\frac{\Delta P}{z}=\frac{2m}{R}\left[\frac{Q(3n+1)}{n\pi R^3}\right]^{n}=\frac{2(2.18\times10^4)}{2.54\times10^{-3}}(129.7)^{0.39}=1.145\times10^{8}\ \text{Pa/m}$$where 129.7 s-1 is the apparent wall shear rate.
  3. (a) Injection pressure vs time. Since ΔP is proportional to the filled length and z ∝ t, the pressure rises linearly:$$\Delta P(t)=\left(\frac{\Delta P}{z}\right)z(t)=1.145\times10^{8}\times0.0592\,t=\boxed{6.78\times10^{6}\,t\ \text{Pa}}$$
  4. Fill time. The front reaches the end when z = L:$$t_{fill}=\frac{L}{0.0592}=\frac{\pi R^2 L}{Q}=\boxed{4.29\ \text{s}}$$
  5. (b) Pressure to fill the runner. Set z = L in the pressure law:$$\Delta P_{fill}=\left(\frac{\Delta P}{z}\right)L=1.145\times10^{8}(0.254)=\boxed{2.91\times10^{7}\ \text{Pa}=29.1\ \text{MPa}\ (\approx4220\ \text{psi})}$$
Injection pressure and penetration depth vs time (both ∝ t)time t (s)injection pressure ΔP (MPa)penetration z (m)0.00.007.90.0715.70.1423.60.2131.40.270.000.861.722.573.434.29ΔP ∝ tz ∝ t (fill)
Fig. 5 — injection pressure (left axis) and penetration depth (right axis) both grow linearly with time; the melt fills the 0.254 m runner at 4.29 s and 29.1 MPa.
QuantityValue
Penetration depthz(t) = 0.0592 t m
Apparent wall shear rate129.7 s-1
Pressure gradient, ΔP/z1.145×108 Pa/m
Injection pressureΔP(t) = 6.78×106 t Pa
Fill time4.29 s
(b) Pressure to fill runner29.1 MPa (≈ 4220 psi)