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18-Env-B4 Site Assessment and Remediation · December 2019

Question 4 of 7: Bioventing for Petroleum Hydrocarbon Remediation

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

National Exams — December 2019 — 18-Env-B4: Site Assessment and Remediation (3 hours, open book). Instructions: answer FOUR of the FIVE Section A questions and ONE of the TWO Section B questions; all eight questions (A-1–A-5, B-1, B-2) are answered in full below as a complete study resource. Each question is worth 20 marks.

Reference texts: Nyer, E.K., Practical Techniques for Groundwater and Soil Remediation; Fetter, C.W., Contaminant Hydrogeology (2nd ed.); Leeson, A. & Hinchee, R.E. (1997), Soil Bioventing: Principles and Practice; CSA Z768-01, Phase I Environmental Site Assessment; British Columbia Contaminated Sites Regulation (Environmental Management Act); Ontario Regulation 153/04 (Records of Site Condition); Canadian Council of Ministers of the Environment (CCME), National Classification System for Contaminated Sites and Canada-Wide Standard for Petroleum Hydrocarbons in Soil; Karickhoff, S.W. (1981), organic-carbon partitioning correlations.

Section A — answer FOUR of FIVE (all five answered)

Question A-4: Bioventing for Petroleum Hydrocarbon Remediation (20 marks)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

Excavated hydrocarbon-impacted soil pile (300 m³, 800 mg/kg avg.)Perforated vent wellBlowerLow-rate air delivery → aerobic biodegradation zoneO₂ / CO₂ monitoring pointBioventing Schematic — excavated pile treatment
Bioventing schematic: a low-flow blower delivers air through a perforated vent well into the vadose zone, stimulating in-situ aerobic biodegradation of sorbed hydrocarbons rather than physically stripping them.

Implementation. Bioventing is implemented in four stages. (1) Site characterization and feasibility: confirm the impact is in the vadose (unsaturated) zone, that soil permeability supports air movement, and that indigenous hydrocarbon-degrading microbial populations are present and not nutrient/moisture-limited. (2) Pilot/respiration testing: a short-term air-injection or -extraction pilot test at a candidate well measures the in-situ oxygen utilization rate (O₂ depletion) and CO₂ generation rate at several radial monitoring points, which sizes both the radius of influence of a single well and confirms biodegradation (not just physical venting) is occurring. (3) Full-scale design: vertical vent wells are installed on a spacing set by the pilot-test radius of influence, screened across the impacted interval; a low-capacity regenerative blower supplies air at a rate set deliberately LOW relative to soil vapour extraction (SVE) — enough to maintain aerobic conditions (typically targeting several percent O₂ in the pore space) without stripping so much vapour that volatilization, rather than biodegradation, becomes the dominant removal mechanism. (4) Operation and monitoring: periodic O₂/CO₂ monitoring at multiple points confirms the aerobic zone is being maintained and biodegradation is progressing, with periodic soil sampling to track hydrocarbon concentration against the clean-up standard, continuing until the target is met.

Why it is effective. Bioventing delivers oxygen — the rate-limiting ingredient for aerobic biodegradation — directly to the indigenous microbial population already present in the impacted soil, rather than relying on natural diffusion, which is far too slow to meet a clean-up timeline. Because the air-flow rate is deliberately kept low, the dominant removal mechanism is in-situ biological destruction of the hydrocarbons (permanent, on-site mineralization to CO₂ and water) rather than physical mass transfer of contaminant to vapour requiring separate off-gas treatment, as SVE typically requires. This makes bioventing comparatively low-cost and low-energy, minimally disruptive to the site (no excavation, minimal infrastructure), and effective on the weathered, less-volatile fractions of a hydrocarbon plume that SVE alone struggles to remove once the more volatile fractions are depleted — a good fit for reducing a hydrocarbon-impacted soil below a numeric clean-up standard without the cost and disruption of excavation.