18-Env-B5 Industrial & Hazardous Waste Management · May 2017
Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
Reference texts: Nemerow & Dasgupta, Industrial and Hazardous Waste Treatment, 2nd ed.; Metcalf & Eddy, Wastewater Engineering: Treatment and Resource Recovery, 5th ed.; Davis & Cornwell, Introduction to Environmental Engineering, 6th ed.; LaGrega, Buckingham & Evans, Hazardous Waste Management, 2nd ed.; CCME, Guidelines for the Management of Biomedical Waste in Canada (1992); Canadian Environmental Protection Act (CEPA), 1999; Canadian Nuclear Safety Commission (CNSC) regulations on radioactive waste under the Nuclear Safety and Control Act; provincial hazardous waste regulations (e.g. BC's Environmental Management Act and Hazardous Waste Regulation).
Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.
Biological treatment needs nitrogen and phosphorus, in addition to the carbon supplied by the organic waste itself, to build new microbial cell mass; a commonly cited minimum ratio for aerobic systems is BOD5 : N : P ≈ 100 : 5 : 1 (by mass). Anaerobic systems need proportionally less nutrient — roughly 100 : 2.5 : 0.5 — because anaerobic biomass yield (cell mass produced per unit substrate consumed) is much lower than aerobic yield. Trace amounts of micronutrients (iron, magnesium, calcium, potassium, and trace metals such as cobalt and nickel for some anaerobic populations) are also required, though these are usually present in sufficient quantity in industrial wastewaters and municipal water supplies without deliberate supplementation. Where the influent BOD:N:P ratio falls short — common for wastewaters low in nitrogen such as many food-processing or pulp-and-paper effluents — nutrients must be dosed externally (e.g. as urea or ammonium salts for N, phosphoric acid or a phosphate salt for P) or the biological process will be nutrient-limited and effluent quality will suffer regardless of organic loading control.