18-Env-B7 Environmental Sampling and Analysis · December 2014
Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
National Exams — December 2014 — 04-Env-B7 / Environmental Sampling and Analysis. 3 hours duration; open book (approved Sharp or Casio calculator only); t-distribution table supplied. Part A (Questions 1–3) is compulsory; Part B (Questions 4–6) asks for any two of three — all six are solved below for completeness. Each question is worth 20 marks.
Reference texts. Walpole, Myers, Myers & Ye, Probability & Statistics for Engineers and Scientists (statistical hypothesis testing, exploratory data analysis); Davis & Cornwell, Introduction to Environmental Engineering (6th ed.) (sampling design, QA/QC, environmental monitoring programs); U.S. EPA Guidance for Choosing a Sampling Design for Environmental Data Collection (QA/G-5S); Canadian Council of Ministers of the Environment (CCME) monitoring and reporting guidance.
Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.
Given. Eleven locations, each measured by both methods (paired data); printed summary for the differences $d_i=A_i-B_i$: $\bar d=-1.809$, $s_d=3.016$, $SE_{\bar d}=0.909$, $n=11$.
| Location | Method A | Method B | $d_i=A_i-B_i$ |
|---|---|---|---|
| 1 | 66.3 | 71.3 | −5.0 |
| 2 | 63.5 | 60.4 | 3.1 |
| 3 | 64.9 | 64.6 | 0.3 |
| 4 | 61.8 | 63.9 | −2.1 |
| 5 | 64.3 | 68.8 | −4.5 |
| 6 | 64.7 | 70.1 | −5.4 |
| 7 | 65.1 | 64.8 | 0.3 |
| 8 | 64.5 | 68.9 | −4.4 |
| 9 | 68.4 | 65.8 | 2.6 |
| 10 | 63.2 | 66.2 | −3.0 |
| 11 | 67.4 | 69.2 | −1.8 |
Find. The appropriate t-test, its test statistic, and the conclusion at $\alpha=0.05$.
Approach. Decide independence vs. pairing first, then apply the matching t-procedure and compare the test statistic to the one-tailed critical value from the supplied t-table.
Method A and Method B were both applied at the same 11 locations – each pair $(A_i,B_i)$ shares a sampling occasion, so the two columns are naturally correlated, not independent. The paired t-test is therefore the statistically appropriate procedure: it works directly on the 11 differences $d_i$, so any location-to-location variation common to both methods cancels out of the comparison, leaving only the true systematic difference between methods. An (incorrect) independent two-sample test would throw away that cancellation and inflate the estimated standard error of the difference.
Conclusion. At the 5% significance level there is a statistically significant difference: Method A reads, on average, about 1.8 ppm lower than Method B ($P\approx0.037\lt 0.05$). The data support the claim that Method A gives lower pollution readings than Method B.
The paired t-test's main assumption is that the population of paired differences $d_i=A_i-B_i$ is (at least approximately) normally distributed. With only $n=11$ pairs, the Central Limit Theorem cannot be relied on to normalize a non-normal difference distribution, so approximate normality of the $d_i$ themselves is required for the t-reference distribution used in part (a) to be valid.
A simple graphical check is a normal probability plot of the 11 differences: each sorted $d_{(i)}$ is plotted against its normal score $z_i=\Phi^{-1}\!\left(\frac{i-0.5}{n}\right)$; if the points fall close to a straight line, normality is a reasonable working assumption.
| Item | Result |
|---|---|
| Appropriate test | Paired t-test (the 11 locations are matched pairs, not independent samples) |
| Test statistic $t$ | −1.99 ($df=10$) |
| Critical value / P-value | $t_{0.05,10}=1.812$; $P\approx0.037$ |
| Conclusion | Reject $H_0$ – Method A reads significantly lower than Method B at 5% |
| Assumption | Paired differences $d_i$ are approximately normally distributed |
| Graphical check | Normal probability plot of $d_i$ – approximately linear, supports normality |