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18-Env-B7 Environmental Sampling and Analysis · December 2014

Question 2 of 6: Paired T-Test for Two CO₂ Measurement Methods

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

National Exams — December 2014 — 04-Env-B7 / Environmental Sampling and Analysis. 3 hours duration; open book (approved Sharp or Casio calculator only); t-distribution table supplied. Part A (Questions 1–3) is compulsory; Part B (Questions 4–6) asks for any two of three — all six are solved below for completeness. Each question is worth 20 marks.

Reference texts. Walpole, Myers, Myers & Ye, Probability & Statistics for Engineers and Scientists (statistical hypothesis testing, exploratory data analysis); Davis & Cornwell, Introduction to Environmental Engineering (6th ed.) (sampling design, QA/QC, environmental monitoring programs); U.S. EPA Guidance for Choosing a Sampling Design for Environmental Data Collection (QA/G-5S); Canadian Council of Ministers of the Environment (CCME) monitoring and reporting guidance.

Question 2: Paired T-Test for Two CO₂ Measurement Methods (20 marks)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

(a) The Appropriate Test and Its Conclusion

Given. Eleven locations, each measured by both methods (paired data); printed summary for the differences $d_i=A_i-B_i$: $\bar d=-1.809$, $s_d=3.016$, $SE_{\bar d}=0.909$, $n=11$.

Paired measurements and differences (ppm CO₂)
LocationMethod AMethod B$d_i=A_i-B_i$
166.371.3−5.0
263.560.43.1
364.964.60.3
461.863.9−2.1
564.368.8−4.5
664.770.1−5.4
765.164.80.3
864.568.9−4.4
968.465.82.6
1063.266.2−3.0
1167.469.2−1.8

Find. The appropriate t-test, its test statistic, and the conclusion at $\alpha=0.05$.

Approach. Decide independence vs. pairing first, then apply the matching t-procedure and compare the test statistic to the one-tailed critical value from the supplied t-table.

Method A and Method B were both applied at the same 11 locations – each pair $(A_i,B_i)$ shares a sampling occasion, so the two columns are naturally correlated, not independent. The paired t-test is therefore the statistically appropriate procedure: it works directly on the 11 differences $d_i$, so any location-to-location variation common to both methods cancels out of the comparison, leaving only the true systematic difference between methods. An (incorrect) independent two-sample test would throw away that cancellation and inflate the estimated standard error of the difference.

  1. Hypotheses. $H_0:\mu_d=0$ vs. $H_a:\mu_d\lt 0$ (one-tailed, since we want to show Method A reads lower than Method B).
  2. Test statistic. $t=\dfrac{\bar d-0}{SE_{\bar d}}=\dfrac{-1.809}{0.909}$ $$t=\boxed{-1.99}\qquad df=n-1=10$$
  3. Critical value and decision. From the supplied t-table at $df=10$, one-tailed $\alpha=0.05$: $t_{0.05,10}=1.812$. Since $|t|=1.99\gt 1.812$ (equivalently $t=-1.99$ falls left of $-1.812$), we reject $H_0$. Cross-checking against the table: $1.99$ lies between $t_{0.05}=1.812$ and $t_{0.025}=2.228$ at $df=10$, so the one-tailed P-value is bracketed between 0.025 and 0.05 (computed exactly, $P\approx0.037$), confirming the rejection.

Conclusion. At the 5% significance level there is a statistically significant difference: Method A reads, on average, about 1.8 ppm lower than Method B ($P\approx0.037\lt 0.05$). The data support the claim that Method A gives lower pollution readings than Method B.

(b) Assumption and Graphical Check

The paired t-test's main assumption is that the population of paired differences $d_i=A_i-B_i$ is (at least approximately) normally distributed. With only $n=11$ pairs, the Central Limit Theorem cannot be relied on to normalize a non-normal difference distribution, so approximate normality of the $d_i$ themselves is required for the t-reference distribution used in part (a) to be valid.

A simple graphical check is a normal probability plot of the 11 differences: each sorted $d_{(i)}$ is plotted against its normal score $z_i=\Phi^{-1}\!\left(\frac{i-0.5}{n}\right)$; if the points fall close to a straight line, normality is a reasonable working assumption.

-6 -4 -2 0 2 4 -2 -1 0 1 2 Difference, d = A minus B (ppm CO2) Normal score (z)
Fig. 1 – Normal probability plot of the 11 paired differences $d_i=A_i-B_i$ (dashed line: least-squares reference). The points track the straight reference line reasonably closely with no strong curvature or isolated extreme point, supporting the normality assumption needed for the paired t-test in part (a).
Final results – Question 2
ItemResult
Appropriate testPaired t-test (the 11 locations are matched pairs, not independent samples)
Test statistic $t$−1.99 ($df=10$)
Critical value / P-value$t_{0.05,10}=1.812$; $P\approx0.037$
ConclusionReject $H_0$ – Method A reads significantly lower than Method B at 5%
AssumptionPaired differences $d_i$ are approximately normally distributed
Graphical checkNormal probability plot of $d_i$ – approximately linear, supports normality