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18-Geol-A1 Mineralogy and Petrology · December 2016

Question 10 of 13: Metamorphism vs. Metasomatism — Exoskarn, Endoskarn and Hornfels

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

EGBC National Exam — Geological Engineering, 04-Geol-A1 Mineralogy and Petrology, 2016-Dec. Closed book; no calculator permitted. Part 1 requires all six 10-mark short-answer questions (60 marks); Part 2 instructs "answer 4 of the 7 ten-mark questions" (40 marks).

Reference texts: Klein & Dutrow, Manual of Mineral Science, 23rd ed. (mineral/silicate structural classification, ore mineralogy); Winter, Principles of Igneous and Metamorphic Petrology, 2nd ed. (magmatic differentiation, phase diagrams, metamorphic reactions and facies, AFM projections, volcanic processes, ophiolites and oceanic crust, subduction-zone/rift/hotspot melting); Nesse, Introduction to Optical Mineralogy, 4th ed. (index-mineral optics).

Question 10 (Part 2, Q4): Metamorphism vs. Metasomatism — Exoskarn, Endoskarn and Hornfels (Part 2 – 10 marks)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

Metamorphism is isochemical: mineralogy and texture change in response to heat, pressure and/or differential stress, but the rock's bulk chemical composition (apart from volatile loss/gain in dehydration or decarbonation reactions) is essentially preserved. Metasomatism is allochemical: the rock's bulk composition itself is changed by fluid-mediated addition and removal of chemical components, independent of any dehydration/decarbonation the rock might also undergo.

Hornfels — the isochemical (metamorphic) product

Hornfels is the fine-grained, non-foliated rock produced by contact (thermal) metamorphism of the country rock: it recrystallizes to new mineral assemblages appropriate to the local temperature, but its bulk composition stays essentially that of the original protolith.

Skarn — the allochemical (metasomatic) product

Skarn is a coarse-grained, Ca–Fe–Mg–Mn calc-silicate rock (garnet, pyroxene, wollastonite, epidote) produced where a hot, chemically active fluid exchanges components between an intrusion and an adjacent carbonate country rock — Si, Fe, Al and Mg typically migrating outward from the pluton and Ca migrating inward.

How they relate

Both processes occur together at the same intrusion–carbonate contact and are driven by the same heat source; they are distinguished only by whether mass was exchanged (metasomatism → skarn, zoned outward from endoskarn through exoskarn) or not (isochemical contact metamorphism → hornfels, typically further from the contact or where the protolith was not a reactive carbonate). A single contact aureole commonly grades outward: endoskarn (in the pluton) → exoskarn (replacing the carbonate nearest the contact) → marble/hornfels (isochemically recrystallized rock further out).