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18-Geol-A1 Mineralogy and Petrology · May 2017

Question 11 of 13: Calc-Alkaline vs. Tholeiitic and Alkaline Rock Series — AFM Diagram

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

EGBC National Exam — Geological Engineering, 04-Geol-A1 Mineralogy and Petrology, 2017-May. Closed book; no calculator permitted. Part 1 requires all five 10-mark short-answer questions (50 marks); Part 2 lists eight questions with instructions to answer "5 of the 7" (a source discrepancy noted on the exam page itself).

Reference texts: Klein & Dutrow, Manual of Mineral Science, 23rd ed. (silicate structural classification, mineral chemistry/formulas); Winter, Principles of Igneous and Metamorphic Petrology, 2nd ed. (magmatic differentiation and mixing, metamorphic agents/facies, volcanic processes, phase equilibria and AFM projections, magma viscosity, layered intrusions, tectonic melting mechanisms).

Question 11: Calc-Alkaline vs. Tholeiitic and Alkaline Rock Series — AFM Diagram (Part 2 – 10 marks)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

The AFM diagram ($\text{A} = \text{Na}_2\text{O}+\text{K}_2\text{O}$, $\text{F} = \text{FeO}+\text{Fe}_2\text{O}_3$(total Fe), $\text{M} = \text{MgO}$) plots the liquid line of descent of an evolving magma series and is the standard tool for separating these families.

Tholeiitic series

Fe-Ti oxide (magnetite) crystallization is delayed (favoured by lower magmatic $f_{\text{O}_2}$, typical of relatively anhydrous mid-ocean-ridge and oceanic-plateau magmas), so early fractional crystallization removes little Fe. The liquid is driven strongly toward the F apex (marked Fe-enrichment) before eventually turning toward A — the classic tholeiitic "Fe-enrichment trend."

Calc-alkaline series

Early crystallization of Fe-Ti oxides (favoured by the higher $f_{\text{O}_2}$ and water content typical of subduction-zone/arc magmas) removes Fe from the liquid from an early stage, strongly suppressing Fe-enrichment. The trend curves more directly toward the A apex with comparatively little excursion toward F — the diagnostic contrast with the tholeiitic trend, and characteristic of most arc (Cascades, Andes) volcanic suites.

Alkaline series

Silica-undersaturated magmas with high total alkalis relative to silica occupy a field displaced toward the A apex from the outset of crystallization, reflecting derivation from small-degree partial melts of enriched mantle, typically in intraplate/rift settings rather than arc or ridge settings.

A (Na₂O+K₂O) F (FeO+Fe₂O₃) M (MgO) Tholeiitic Calc-alkaline primitive basalt Tholeiitic trend swings toward F (delayed oxide crystallization); calc-alkaline trend suppresses Fe-enrichment via early magnetite crystallization.
AFM diagram: the tholeiitic differentiation trend shows strong early Fe-enrichment (swing toward F) before turning toward A; the calc-alkaline trend, with early Fe-Ti oxide fractionation, moves more directly toward A. Alkaline suites plot displaced toward A from the start of crystallization (not shown as a separate liquid line of descent here, since alkaline magmas follow a distinct primary liquid path rather than a comparable fractionation trend).