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04-Geol-B6 · December 2014

Question 1 of 7: Section 1: Source Rock Geology and Characteristics

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

EGBC National Exam — Geological Engineering, 04-Geol-B6-1 Petroleum Deposits, 2014-Dec. Closed book; Casio/Sharp approved calculator only; 3 hours.

Reference texts: Selley & Sonnenberg, Elements of Petroleum Geology, 3rd ed. (source rocks, generation, migration, traps ch.3-9); Tissot & Welte, Petroleum Formation and Occurrence, 2nd ed. (kerogen types, thermal maturation, oil/gas windows ch.II-IV); Allen & Allen, Basin Analysis, 3rd ed. (migration, petroleum systems ch.9-10); Bjørlykke, Petroleum Geoscience, 2nd ed. (diagenesis, siliciclastic & carbonate reservoirs ch.8-14); Tearpock & Bischke, Applied Subsurface Geological Mapping, 2nd ed. (structural trap geometry ch.10-13); Nichols, Sedimentology and Stratigraphy, 2nd ed. (deltas, carbonate platforms ch.15-17).

Section 1: Source Rock Geology and Characteristics (20 Marks)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

Q1-1 — Depositional conditions for organic-matter accumulation and preservation. Preservation of organic matter (OM) is governed by the classic productivity-preservation-dilution balance: (1) anoxic to dysoxic bottom water is the single most important control — without free oxygen, aerobic bacteria cannot oxidize OM as fast as it is buried, so a much larger fraction survives burial; (2) high primary productivity in the overlying water column (upwelling zones, nutrient-rich lakes) supplies abundant OM in the first place, which can locally drive bottom water anoxic simply by consuming oxygen during its own decay; (3) fine-grained, low-energy, quiet-water settings (below storm wave base) avoid winnowing/reworking that would expose buried OM to oxidation and avoid diluting it with coarse clastic input; and (4) a moderate sedimentation rate that buries OM quickly enough to remove it from the oxidizing zone, but not so fast that it dilutes TOC (total organic carbon) below an economic threshold. Water-column stratification (density, salinity or thermal) that suppresses vertical mixing and oxygen resupply to bottom water is the physical mechanism that most commonly produces conditions (1)-(3) together.

Q1-2 — Kerogen types and their hydrocarbon products. Kerogen is classified by its van Krevelen H/C and O/C ratios into four types reflecting the organic precursor:

TypePrecursor / originH/CDominant product on maturation
Type ILacustrine algal (e.g. Botryococcus) & amorphous liptinitehigh (>1.4)Waxy, paraffinic light oil (best oil-prone)
Type IIMarine planktonic algae & zooplankton, some bacterial reworkingmoderate (≈1.2-1.4)Oil, with associated gas
Type IIITerrestrial higher-plant material (woody, lignin/cellulose-rich)low (≈0.7-1.0)Gas, minor waxy oil; coal-forming
Type IVRecycled/oxidized OM (inertinite, charcoal)very low (<0.6)Inert – negligible hydrocarbon yield

The controlling difference is the H/C ratio inherited from the precursor biomass: algal/lipid-rich Type I/II material is hydrogen-rich and cracks preferentially to liquid hydrocarbons, while lignin- and cellulose-rich terrestrial Type III material is hydrogen-poor and yields mostly gas.

Q1-3 — Four settings that accumulate large volumes of organic matter (source-rock precursors).

oxic epilimnionthermocline / chemoclineanoxic hypolimnionTOC-rich mud (Type I/II)(a) Lacustrine rift lakestratified, wave-sheltered, anoxic bottom wateroxic surface wateroxygen-minimum zoneslope / basin floor waterblack shale (Type II)(b) Deep marine / OMZdistal shelf-slope-basin; low clastic dilution, OMZ impinges on slopedelta plain (channels)delta front sandprodelta mudorganic mud (Type III)(c) Deltaic / prodeltahigh sedimentation rate buries terrestrial OM fastnormal-salinity inflowsill (restricts exchange)stagnant anoxic layerlaminated organic mud (I/II)(d) Restricted / silled basinsill starves basin of oxygen; density-stratified, Black-Sea-type
Four settings that preserve organic-rich mud: stratification and/or a sill keeps bottom water anoxic (a, b, d) or burial is simply too fast for oxidation to consume the organic matter (c).

(a) Lacustrine rift lake. Deep, thermally or chemically stratified lakes (common in early-rift half-graben basins) develop a permanent or seasonal chemocline; below it, the hypolimnion is cut off from atmospheric oxygen resupply and becomes permanently anoxic, so the abundant algal productivity in the sunlit epilimnion above rains down and is preserved almost entirely undegraded — the classic source of Type I kerogen.

(b) Deep marine setting beneath an oxygen-minimum zone (OMZ). On a distal shelf-slope-basin profile, an OMZ (a mid-water oxygen minimum sustained by high surface productivity consuming O2 as it sinks, combined with sluggish deep circulation) can impinge directly on the slope or basin floor. Sedimentation there is slow and clastic-starved, so OM is not diluted, and bottom water is oxygen-depleted, so it is preserved — producing marine Type II source rocks.

(c) Deltaic / prodelta setting. Here preservation is achieved less by anoxia and more by burial speed: the very high sedimentation rates typical of a delta front bury terrestrial (Type III) organic matter delivered by the river so rapidly that oxidizing bacteria simply run out of time before it passes below the oxidized surface layer, even though prodelta bottom water itself is often only weakly dysoxic.

(d) Restricted, silled marine basin. A submarine sill (a Black-Sea-type or evaporitic silled basin) restricts water exchange with the open ocean, allowing a stable density-stratified water column to develop; the isolated deep water below the sill becomes progressively anoxic as it is never flushed, preserving finely laminated (unbioturbated) organic-rich mud — commonly Type I/II depending on whether algal or mixed marine input dominates.

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