21-Mat-A3 Structure and Characterization of Materials · Dec-12-Mtl-A3 2018
Question 2 of 8
Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
Notes on this paper
Paper format. National Exams, December 2018 — 12-Mtl-A3, Structure and Characterization of Materials. Three hours, open book, any non-communicating calculator permitted. Eight questions constitute a complete exam paper; all eight are solved here.
Reference texts. The answers below are keyed to the standard undergraduate materials-science references recommended for this syllabus code:
W. D. Callister Jr. and D. G. Rethwisch, Materials Science and Engineering: An Introduction, 10th ed. — crystal structure and defects (Ch. 4), mechanical properties and fracture (Ch. 6, 8), phase diagrams (Ch. 9), diffraction (Ch. 3), polymer structure and mechanical behaviour (Ch. 14–15).
B. D. Cullity and S. R. Stock, Elements of X-Ray Diffraction, 3rd ed. — structure-factor selection rules for cubic lattices.
Given. FCC lattice; close-packed slip plane (111); candidate slip directions are the twelve signed permutations of the <110> family.
Find. Which <110>-type directions $[uvw]$ actually lie in the (111) plane, i.e. form a valid FCC {111}<110> slip system.
Approach. A direction $[uvw]$ lies in a plane $(hkl)$ if and only if the zone law is satisfied: $hu+kv+lw=0$. Apply this with $(hkl)=(111)$ to every signed permutation of $\{1,1,0\}$.
Part (a) — apply the zone law. For (111), the condition is $u+v+w=0$. Testing the twelve signed <110> vectors: $[110]$ gives $1+1+0=2\neq0$ (out of plane); $[1\bar10]$ gives $1-1+0=0$ (in plane); and so on. Carrying this through the full family leaves exactly six vectors satisfying the condition, forming three independent lines (each line counted once, since $[uvw]$ and $[\bar u\bar v\bar w]$ describe the same crystallographic direction):
$$\boxed{[\bar110],\quad[10\bar1],\quad[01\bar1]}$$
Part (a) — physical check. These three directions are mutually at $120^\circ$ in the (111) plane (each pair's dot product is $\tfrac12$ of the product of magnitudes, consistent with $\cos60^\circ$ between the positive vectors, i.e. $120^\circ$ between the slip-direction lines), matching the three edges of the close-packed triangular (111) net. This is the FCC {111}<110> slip system: 4 distinct {111} planes $\times$ 3 <110> directions each $=12$ independent slip systems, which is why FCC metals (Cu, Al, Ag, Ni, austenitic steel) are so ductile.
Part (b) — sketch. See the figure: the (111) plane forms an equilateral triangle of close-packed atoms, and the three valid <110> directions run along its three edges.
The (111) close-packed plane (triangle) with the three <110>-type directions that lie within it, each 120° from the next — the FCC {111}<110> slip system.