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21-Mat-A4 Deformation Behaviour and Properties of Materials · May 2014

Question 8 of 8: Question VIII — Dislocations and Grain Boundaries (20 marks)

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

Paper format. National Exams, May 2014 — 10-Met-A4, Structure of Materials. Three hours, closed book, one approved calculator (Casio or Sharp). Eight questions of 20 marks each; the rubric asks for any five, and only the first five in the answer book are marked. All eight are solved here, because this set is a study resource rather than an exam script. All necessary equations, constants and the error-function table are provided in the exam's own appendix and are used directly below.

Note on the exam title. The printed exam header reads 10-Met-A4, Structure of Materials. Only two of the eight questions (VI and VIII) are substantially deformation/mechanical-properties content; the paper as a whole is a broad introductory materials-science survey — bonding, crystallography, polymers, diffusion, XRD, phase diagrams, dislocations — and is answered as such below.

Check — figure-read values. Question VI.3's stress-strain curve and Question VII's Cu–Ag solvus/liquidus positions are read from the printed figures rather than given numerically. Graphically-read values carry a few percent uncertainty that closed-form calculations do not — this is flagged again at the point of use.

Reference texts. The answers below are keyed to the works normally recommended for this syllabus code:


Question VIII — Dislocations and Grain Boundaries (20 marks)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

VIII.1 — Full vs. partial dislocations; tilt vs. twist boundaries

Full (perfect) dislocation. Its Burgers vector connects one lattice point to another equivalent lattice point, so slip leaves the crystal structure unchanged after the dislocation passes — e.g. in FCC metals (Cu, Al, Ni) the perfect Burgers vector is $\mathbf{b}=\tfrac{a}{2}\langle110\rangle$, the shortest full lattice translation. Partial dislocation. Its Burgers vector does not connect equivalent lattice points, so its passage leaves a stacking fault (a local region of incorrect stacking sequence) in its wake; a perfect dislocation can dissociate into two Shockley partials bounding a stacking-fault ribbon, e.g. in FCC metals $\tfrac{a}{2}[\bar{1}01] \to \tfrac{a}{6}[\bar{2}11]+\tfrac{a}{6}[\bar{1}\bar{1}2]$ — low-stacking-fault-energy metals such as austenitic stainless steel and brass widely dissociate this way, which widens the stacking-fault ribbon and suppresses cross-slip.

⊥ b Edge dislocation Tilt boundary rotation axis in the boundary plane Twist boundary rotation axis perp. to boundary
Left: edge dislocation — an extra half-plane of atoms (red) terminates at the dislocation line ($\perp$ symbol), with Burgers vector $\mathbf{b}$ perpendicular to the line. Centre: tilt boundary, a low-angle boundary describable as an array of edge dislocations, formed by rotating two grains about an axis lying in the boundary plane. Right: twist boundary, formed by rotating about an axis perpendicular to the boundary (an array of screw dislocations), shown here as the moiré overlap of two grids viewed face-on.

Tilt boundary. A low-angle grain boundary produced when two adjacent grains are misoriented by a small rotation about an axis lying within the boundary plane; it can be modelled as a simple vertical array of parallel edge dislocations spaced $D=b/\theta$ apart ($\theta$ = tilt angle, $b$ = Burgers vector magnitude). Twist boundary. Produced by a small rotation about an axis perpendicular to the boundary plane; it is modelled as a cross-grid (mesh) of screw dislocations rather than a single array, since the misorientation has no in-plane rotation axis to align a single dislocation family with.

VIII.2 — Hall-Petch strengthening and grain-growth kinetics

Given. $\sigma_y = \sigma_i + k_yd^{-1/2}$, $\sigma_i=3$ MPa, $k_y=0.5\ \text{MPa}\cdot\text{m}^{1/2}$; $d_0=4\ \mu\text{m} \to d=103.82\ \mu\text{m}$ after annealing. Grain growth: $d^n-d_0^n=Kt$, $n=4$, $K=4.4\ \mu\text{m}^4/\text{s}$.

Find. (a) % decrease in yield strength on annealing; (b) time $t$ for the anneal.

Approach. (a) Evaluate Hall-Petch before and after (converting $d$ to metres). (b) Solve the grain-growth law directly for $t$ (keeping $d,d_0$ in $\mu$m to match $K$'s units).

  1. (a) Yield strength before and after annealing. $$\sigma_y^{as} = 3 + \frac{0.5}{\sqrt{4\times10^{-6}}} = 3+250 = \boxed{253\ \text{MPa}}$$ $$\sigma_y^{ann} = 3 + \frac{0.5}{\sqrt{103.82\times10^{-6}}} = 3+49.07 = \boxed{52.1\ \text{MPa}}$$ $$\%\,\text{decrease} = \frac{253-52.1}{253}\times100 = \boxed{79.4\%}$$
  2. (b) Annealing time. $$t = \frac{d^n-d_0^n}{K} = \frac{(103.82)^4-(4.0)^4}{4.4} = \boxed{2.64\times10^7\ \text{s} \approx 305.6\ \text{days}}$$ The grain must grow by a factor of $26\times$ in linear size (fourth-power kinetics), so even with $K$ expressed per second the anneal is physically a many-month, furnace-scale heat treatment, not a quick temper.
Question VIII — final results
QuantityValue
$\sigma_y$, as-received ($d=4\ \mu$m)$253$ MPa
$\sigma_y$, annealed ($d=103.82\ \mu$m)$52.1$ MPa
% decrease in yield strength$79.4\%$
Annealing time, $t$$2.64\times10^7$ s $\approx 305.6$ days
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