24-Pet-A3 Fundamental Reservoir Engineering · Undated paper
Question 2 of 7: Capillary Pressure, Solution GOR, and Core Saturation Volumes
Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
Notes on this paper
17-Pet-A3 — Fundamental Reservoir Engineering · National Exams, May 2019 · 3 hours, closed book, approved Casio/Sharp calculator only · seven questions provided; five (5) questions constitute a complete exam paper (the first five as they appear in the answer book are marked), all questions equal value (20 marks each), all parts of a multipart question equal weight. All seven questions are answered below.
Reference texts: Craft, B.C. & Hawkins, M.F., Applied Petroleum Reservoir Engineering, 3rd ed. (material balance, Darcy flow, relative permeability); Ahmed, T., Reservoir Engineering Handbook, 5th ed. (material balance, gas PVT, decline-curve analysis); Lyons, W.C. (ed.), Standard Handbook of Petroleum and Natural Gas Engineering, 3rd ed.; McCain, W.D., The Properties of Petroleum Fluids, 3rd ed. (PVT properties, capillary pressure).
(2) Initial pressure / bubble point, $p_i$ / $p_b$
3,000 / 2,500 psig
(2) Gas solubility, $dR_s/dp$
0.25 SCF/STB/psi
(3) Porosity / bulk volume / $S_w$
0.20 / 50 cm³ / 17%
(4) Core length / diameter
15 cm / 2.5 cm
(4) Dry / saturated mass
153.0 g / 167.7 g
Fig. Q2(1): gas slug trapped against the sealed left end of a water-filled capillary; the meniscus curves toward the (non-wetting) gas phase since water wets the tube wall at θ=15°.
Find. (1) gas-phase pressure $P_g$; (2) initial solution gas-oil ratio $R_{si}$; (3) oil volume in the core; (4) core porosity from the mass-imbibition method.
Approach. Each sub-part is a direct application of a single governing relation: capillary pressure across a curved interface, the linear solubility of gas in an under-saturated oil below its bubble point, saturation-weighted pore volume, and the mass-balance definition of porosity.
(1) Capillary pressure and gas-phase pressure. Water is the wetting phase (small contact angle), so the meniscus curves toward the gas and $P_c=P_g-P_w=\dfrac{2\sigma\cos\theta}{r}$, with $r=d/2=5\times10^{-6}$ m: $P_c=\dfrac{2(0.072)\cos15^\circ}{5\times10^{-6}}=27{,}819$ Pa $=27.82$ kN/m². Then $\boxed{P_g=P_w+P_c=110+27.82=137.8\ \text{kN/m}^2}$.
(2) Initial solution GOR. Above the bubble point the oil is a single liquid phase, so $R_s$ is constant at its bubble-point value; taking the standard linear solubility model ($R_s=0$ at atmospheric pressure, rising linearly to $R_{sb}$ at $p_b$) with the given slope, $\boxed{R_{si}=R_{sb}=\left(\dfrac{dR_s}{dp}\right)p_b=0.25(2{,}500)=625\ \text{SCF/STB}}$.
(3) Oil volume in the core. With only oil and water present, $S_o=1-S_w=1-0.17=0.83$: $V_o=\phi\,V_b\,S_o=0.20(50)(0.83)$, so $\boxed{V_o=8.3\ \text{cm}^3}$.
(4) Porosity by mass imbibition. Pore volume equals the mass of water imbibed divided by water density: $V_p=\dfrac{m_{sat}-m_{dry}}{\rho_w}=\dfrac{167.7-153.0}{1.00}=14.7\ \text{cm}^3$. Bulk volume $V_b=\pi r^2 L=\pi(1.25)^2(15)=73.63\ \text{cm}^3$. So $\boxed{\phi=V_p/V_b=14.7/73.63=0.1996\approx20.0\%}$.
Quantity
Value
(1) Gas-phase pressure, $P_g$
137.8 kN/m²
(2) Initial solution GOR, $R_{si}$
625 SCF/STB
(3) Oil volume in core
8.3 cm³
(4) Core porosity
0.1996 (20.0%)
Check: part (2) assumes the textbook simplification that solution gas-oil ratio varies linearly with pressure from $R_s=0$ at 0 psig up to $R_{sb}$ at the bubble point, using the given constant solubility as that slope — the exam supplies no other reference point (e.g. a stock-tank flash GOR) to anchor the line, so this is the standard assumption for this problem type.