17-Phys-B6 Applied Thermodynamics and Heat Transfer · December 2013
Question 4 of 8: Freon-12 Vapour-Compression Refrigeration Cycle
Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
Notes on this paper
Paper format. 98-Phys-B6 Applied Thermodynamics and Heat Transfer,
National Examination December 2013 — a three-hour open-book examination;
candidates are expected to bring both a thermodynamics text and a heat-transfer text to make use
of the property tables. A complete examination is five questions — either three from Part A
(Thermodynamics, Q1–Q4) and two from Part B (Heat Transfer, Q5–Q8), or two from Part A
and three from Part B — every question carrying equal value; all eight are solved below as a
complete study set. Candidates are invited to state any assumptions where a question is open to
interpretation; this licence is used explicitly in Question 1(b) (standard air properties, not
printed directly) and Question 7 (a printed convective "rate" read as a heat-transfer coefficient
with a temperature unit omitted in print — the same omission the paper shows in Question 6's specific-heat units).
Reference texts. Y. A. Çengel and M. A. Boles, Thermodynamics: An
Engineering Approach, 8th ed. (ideal-gas processes, vapour power cycles, gas-turbine/Brayton
cycles, vapour-compression refrigeration); F. P. Incropera and D. P. DeWitt, Fundamentals of
Heat and Mass Transfer, 7th ed. (conduction, natural convection, lumped-capacitance transient
conduction, radiation exchange between surfaces, heat-exchanger LMTD analysis).
Given. Mass flow rate 0.04 kg/s; compressor inlet 150 kPa/$-10\,{}^{\circ}\text{C}$;
compressor exit 1.2 MPa/75°C; expansion-valve inlet 1.15 MPa/40°C (subcooled liquid, since
$T_{\text{sat}}$ at 1.15 MPa is about $47\,{}^{\circ}\text{C}$); evaporator exit 175 kPa/$-15\,{}^{\circ}\text{C}$
(a distinct, slightly higher-pressure state than the compressor inlet — a realistic
suction-line pressure drop); actual compressor power 1.9 kW.
Given data
State
Description
Condition
comp. in
Compressor inlet
150 kPa, $-10\,{}^{\circ}\text{C}$
comp. out
Compressor exit
1.2 MPa, $75\,{}^{\circ}\text{C}$
valve in
Expansion-valve inlet
1.15 MPa, $40\,{}^{\circ}\text{C}$
evap. out
Evaporator exit
175 kPa, $-15\,{}^{\circ}\text{C}$
—
Mass flow rate
$\dot m=0.04$ kg/s
—
Actual compressor power
$\dot W_c=1.9$ kW
Find. (a) $\Delta s$ across the compressor; (b) refrigeration capacity
$\dot Q_{evap}$; (c) COP; (d) heat lost by the refrigerant per unit mass while passing through
the compressor.
T–s diagram, drawn to scale from R-12 properties: 1→2 compression
(150 kPa, $-10\,{}^{\circ}\text{C}$ to 1.2 MPa, $75\,{}^{\circ}\text{C}$; dashed — real, non-adiabatic)
· 2→3 condenser (desuperheat, condense, subcool to $40\,{}^{\circ}\text{C}$ at 1.15 MPa) ·
3→4 throttling valve (constant $h$, dashed) · 4→5 evaporator at 175 kPa to
$-15\,{}^{\circ}\text{C}$ · 5→1 suction line (pressure drop to 150 kPa).
Approach. Read every state from the paper's own R-12 appendix (Appendix 2,
superheated Freon-12; Appendix 3, saturated Freon-12), interpolating where a state falls between
tabulated rows. The valve is isenthalpic, so the evaporator-inlet enthalpy equals the valve-inlet
enthalpy. Compressor entropy change, the evaporator's own energy balance, COP, and the
compressor's energy balance (with heat loss) follow directly. State numbers follow the figure:
1 compressor inlet, 2 compressor exit, 3 valve inlet, 4 evaporator inlet, 5 evaporator exit.
State properties from the appendix.
State 1 (150 kPa, $-10\,{}^{\circ}\text{C}$; superheated, $T_{sat}\approx-20\,{}^{\circ}\text{C}$):
tabulated directly in the 0.15 MPa column, $h_1=184.619$ kJ/kg, $s_1=0.7313$ kJ/kg·K.
State 2 (1.2 MPa, $75\,{}^{\circ}\text{C}$): midway between the 70 and $80\,{}^{\circ}\text{C}$ rows of the
1.20 MPa column, $h_2=(222.687+230.398)/2=226.543$ kJ/kg, $s_2=(0.7293+0.7514)/2=0.7404$ kJ/kg·K.
State 3 (1.15 MPa, $40\,{}^{\circ}\text{C}$): compressed liquid ($T_{sat}$ at 1.15 MPa is about
$47\,{}^{\circ}\text{C}$), taken as saturated liquid at the same temperature, $h_3\approx h_f(40\,{}^{\circ}\text{C})=74.527$ kJ/kg.
State 5 (175 kPa, $-15\,{}^{\circ}\text{C}$): interpolating the saturation table between
$-20\,{}^{\circ}\text{C}$ (0.1509 MPa) and $-15\,{}^{\circ}\text{C}$ (0.1825 MPa) gives
$T_{sat}(175\text{ kPa})=-16.19\,{}^{\circ}\text{C}$ and $h_g=180.315$ kJ/kg, so the vapour is
superheated by 1.19 K; with the vapour specific heat implied by the 0.10 MPa column,
$(185.707-179.361)/10=0.635$ kJ/kg·K,
$$h_5=180.315+0.635\times1.19=181.068\text{ kJ/kg}$$
Part (a) — entropy change across the compressor.
$$\boxed{\Delta s = s_2-s_1 = 0.7404-0.7313 = 0.0090\text{ kJ/kg}\cdot\text{K}}$$
A small positive change, consistent with an irreversible (non-isentropic) real compression; it is
small because the heat the compressor loses (part (d)) carries entropy out.
Part (b) — refrigeration capacity. The valve is throttled at constant
enthalpy, so $h_4=h_3=74.527$ kJ/kg. The refrigeration effect is the enthalpy rise across the
evaporator itself, from its inlet (state 4) to its own exit (state 5) — not to the
compressor inlet, which lies downstream of a suction-line pressure drop:
$$\dot Q_{evap} = \dot m\,(h_5-h_4) = 0.04\times(181.068-74.527) = 0.04\times106.541$$
$$\boxed{\dot Q_{evap} = 4.26\text{ kW}}$$
Part (c) — coefficient of performance. COP uses the ACTUAL compressor
power (given directly), not an ideal isentropic estimate:
$$\boxed{\text{COP} = \frac{\dot Q_{evap}}{\dot W_c} = \frac{4.262}{1.9} = 2.24}$$
Part (d) — heat lost through the compressor casing. The compressor's
own enthalpy rise,
$$\Delta h_{comp} = h_2-h_1 = 226.543-184.619 = 41.924\text{ kJ/kg}$$
is LESS than the actual specific work supplied,
$$w_{in} = \frac{\dot W_c}{\dot m} = \frac{1.9}{0.04} = 47.500\text{ kJ/kg}$$
The steady-flow energy equation $q-w=\Delta h$ (with $w=-w_{in}$, work done on the fluid) gives
$$q = \Delta h_{comp} - w_{in} = 41.924-47.500$$
$$\boxed{q = -5.58\text{ kJ/kg (a heat LOSS of about 5.6 kJ/kg to the surroundings)}}$$
The extra work supplied beyond the enthalpy rise leaves the refrigerant as heat through the
compressor casing, rather than showing up as additional gas heating.
Check: Cross-check against a modern equation of state. Its
absolute $h$ and $s$ values sit on a different reference state (about 165 kJ/kg and
0.86 kJ/kg·K above this appendix), which cancels in every difference used here. The
differences give $\Delta s=0.0088$ kJ/kg·K, $\dot Q_{evap}=4.276$ kW, COP $=2.251$ and
$q=-5.315$ kJ/kg — within 0.5% of the appendix-based capacity and COP. The heat loss differs by
about 0.26 kJ/kg (5%) because it is a small difference between two large numbers
(41.9 vs 47.5 kJ/kg). Answers from either property source are acceptable; the appendix values
above are the ones this paper supplies.