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23-Chem-A1 Process Balances and Chemical Thermodynamics · Undated paper

Question 1 of 6: Auditorium Air-Conditioning — Recycle Humidity Balance

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

Reference texts: Felder, Rousseau & Bullard, Elementary Principles of Chemical Processes (4th ed., Wiley) — psychrometric (humidity) mass balances with recycle, fuel/air combustion stoichiometry, and waste-heat sensible-energy balances; Smith, Van Ness, Abbott & Swihart, Introduction to Chemical Engineering Thermodynamics (8th ed., McGraw-Hill) — the van der Waals equation of state with one-fluid mixing rules and the reaction-equilibrium constant from standard Gibbs energies; critical-property data from Poling, Prausnitz & O’Connell, The Properties of Gases and Liquids (5th ed.).

Paper structure. 16-CHEM-A1, May 2019, three hours, open book. Part A (Process Mass and Energy Balances) has three questions and Part B (Chemical Thermodynamics) has three. The printed numbering restarts at 1 in Part B, and the cover note reads “Part B (Questions 4 and 6)”. Candidates answer TWO questions from each part; four questions make a complete paper, each of equal value. All six questions are worked below, labelled A1–A3 and B1–B3.

Part A — Process Mass and Energy Balances

Question A1: Auditorium Air-Conditioning — Recycle Humidity Balance (25 points)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

Given. A mixing tee combines fresh air with recycled auditorium exhaust; the mixed air is cooled and dehumidified in the A/C plant and supplied to the auditorium, where occupants add moisture. Total pressure 1 atm throughout. The molar humidities (mol H₂O per mol dry air) are the load-bearing data:

StreamConditionMolar humidity $H$ (mol/mol dry air)
Fresh air (F)35 °C, 70% RH, 4,500 m³/hr$H_F=0.0405$
Mixed air (M)29.5 °C, 54% RH$H_M=0.0225$
Supply to auditorium (in)17 °C, 83.5% RH, 20,900 m³/hr$H_{in}=0.0163$
Leaving auditorium / recycle (out)27 °C, 50% RH$H_{out}=0.0181$

Find. (a) the water condensed in the A/C plant; (b) the water picked up in the auditorium; (c) the recycle-to-fresh air ratio.

Mixing teeA/C plant(cool + dehumidify)Auditorium27 C, 50% RHFresh air4500 m3/h, 35 CH_F=0.0405Mixed air29.5 C, H_M=0.0225Supply20900 m3/h, 17 CH_in=0.0163Recycle RH_out=0.0181ExhaustCondensate(moisture removed)
Figure 1 — The air-conditioning loop: fresh make-up and recycled room exhaust blend at the mixing tee, are cooled and dehumidified in the plant (condensate = moisture removed), and are supplied to the auditorium where occupants add moisture. Dry air is conserved on every arrow and is used as the tie component.

Approach. Dry air is conserved across every unit, so it is the natural tie: fix the dry-air molar flow from the supply stream, apply it to the humidity change across the plant and across the room, then close a water balance on the mixing tee to get the recycle ratio.

  1. Dry-air molar flow through the plant and room. The 20,900 m³/hr supply is humid air at 17 °C (290.15 K), 1 atm. By the ideal-gas law the total molar flow is $$n_{tot}=\frac{P\dot V}{RT}=\frac{(101{,}325)(20{,}900)}{(8.314)(290.15)}=8.779\times10^{5}\ \text{mol/hr},$$ and removing the water gives the dry-air flow $$\dot n_{da}=\frac{n_{tot}}{1+H_{in}}=\frac{8.779\times10^{5}}{1.0163}=\boxed{8.638\times10^{5}\ \text{mol/hr}}.$$ This same dry air passes through the plant and then through the auditorium.
  2. (a) Moisture removed in the A/C plant. Across the plant the dry air is unchanged while its humidity falls from $H_M$ to $H_{in}$, so the water condensed is $$\dot n_{H_2O}=\dot n_{da}(H_M-H_{in})=8.638\times10^{5}(0.0225-0.0163)=5{,}356\ \text{mol/hr},$$ i.e. $5{,}356\times18.015=$ 96.5 kg/hr of moisture removed.
  3. (b) Moisture added in the auditorium. Between supply and exhaust the humidity rises from $H_{in}$ to $H_{out}$ on the same dry-air flow: $$\dot n_{H_2O}=\dot n_{da}(H_{out}-H_{in})=8.638\times10^{5}(0.0181-0.0163)=1{,}555\ \text{mol/hr}=\boxed{28.0\ \text{kg/hr added}}.$$
  4. (c) Recycle ratio from the mixing-tee lever. On the tee, dry air and water both balance: with $F$, $R$, $M$ the dry-air flows of fresh, recycle and mixed streams, $F+R=M$ and $F\,H_F+R\,H_{out}=M\,H_M$. Eliminating $M$ gives the classic lever-arm result $$\frac{R}{F}=\frac{H_F-H_M}{H_M-H_{out}}=\frac{0.0405-0.0225}{0.0225-0.0181}=\frac{0.0180}{0.0044}=\boxed{4.09}.$$ About four moles of air are recycled per mole of fresh make-up. On a total (humid) mole basis the ratio is $4.09(1.0181)/(1.0405)=4.00$.
  5. Consistency cross-check. The fresh feed of 4,500 m³/hr at 35 °C carries $\dot n_{da,F}=\dfrac{(101{,}325)(4{,}500)}{(8.314)(308.15)(1.0405)}=1.710\times10^{5}$ mol/hr dry air. Closing the dry-air balance on the tee ($R=\dot n_{da}-F=6.93\times10^{5}$) gives $R/F=4.05$. That agrees with the humidity lever to within 1%, so the volumetric flows and the humidity data are consistent. The problem is over-specified, and the lever value 4.09 is quoted because it uses the stated humidities directly.
Check: the recycle stream is taken at the auditorium-exit humidity $H_{out}=0.0181$ (the exhaust that is split into recycle + purge), and dry air is assumed conserved in each unit (only water is added or condensed). Both are standard psychrometric assumptions consistent with the stated stream data.
QuantityResult
Dry-air molar flow (plant & room)$8.64\times10^{5}$ mol/hr (863.8 kmol/hr)
(a) Moisture removed in A/C plant5,356 mol/hr = 96.5 kg/hr
(b) Moisture added in auditorium1,555 mol/hr = 28.0 kg/hr
(c) Recycle ratio (dry-air basis)4.09 (flow cross-check 4.05; humid-mole basis 4.00)
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