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23-Chem-A2 Unit Operations and Separation Processes · May 2013

Question 4 of 6: Section B — Thermal Operations

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

Paper format. National Exam 04-Chem-A2 Mechanical and Thermal Operations, May 2013 — open-book, 3 hours. Two sections: Section A (Mechanical Operations, A1–A3) and Section B (Thermal Operations, B1–B3); all problems 25 marks. The rubric asks candidates to attempt two problems per section; all six are solved in full below.

Reference texts: McCabe, Smith & Harriott, Unit Operations of Chemical Engineering (7th ed., McGraw-Hill) — pipe-flow friction, loss coefficients, sphericity and the Ergun equation (Tables 7.1, 5.1); de Nevers, Fluid Mechanics for Chemical Engineers (3rd ed.) and Brodkey & Hershey, Transport Phenomena — mechanical-energy balance and sudden expansion/contraction losses; Incropera & DeWitt, Fundamentals of Heat and Mass Transfer (7th ed., Wiley) — composite-wall resistance networks, LMTD/ε–NTU cross-flow exchangers and lumped radiative cooling; Lienhard, A Heat Transfer Textbook and Özişik, Radiative Transfer for the appended correction-factor and emissivity charts.

Compressible-flow note. Water properties at 180 °F are taken as $\rho=60.55\ \mathrm{lb/ft^3}=970\ \mathrm{kg/m^3}$ and $\mu=2.32\times10^{-4}\ \mathrm{lb/(ft\cdot s)}=3.45\times10^{-4}\ \mathrm{Pa\cdot s}$; commercial-steel roughness $\varepsilon=0.0457$ mm (Table A2).

Section A — Mechanical Operations

Section B — Thermal Operations

Question B1: Composite Wall — Thermal Circuit, Heat Rate and Interface Temperatures (25 marks)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

Given. Wall depth 1 m (into page), $H=3$ m.

QuantityValue
Layer thicknesses $L_1/L_2/L_3$0.05 / 0.10 / 0.05 m
Conductivities $k_A=k_D$ / $k_B$ / $k_C$50 / 10 / 1 W m$^{-1}$K$^{-1}$
Convection $h_1$ / $h_2$50 / 10 W m$^{-2}$K$^{-1}$
Fluid temperatures $T_{\infty,1}$ / $T_{\infty,2}$200 / 25 °C
B, C sub-heights $H_B=H_C$1.5 m each

Find. (a) the resistance network; (b) heat rate $q$ and interface temperatures $T_1$ (A–middle) and $T_2$ (middle–D); (c) replacement C-thickness for the same $q$.

A B C D L₁L₂L₃ T∞,1 h₁T∞,2 h₂ H Thermal circuit (part a) T∞,1 R⁏₁ Rᵤ T₁ Rᵦ Rᶜ T₂ Rᵛ R⁏₂ T∞,2
Figure B1 — The wall and its resistance network: convection, A, the parallel pair B‖C, D and convection in series. B and C share the same two faces (isothermal surfaces), so they are in parallel.

Approach. Build the series–parallel resistance network (per-unit-depth areas), sum to a total resistance, then $q=\Delta T/R_{\text{tot}}$; interface temperatures follow by walking the network from either side.

  1. (a) Individual resistances (area = height × 1 m depth; $R=L/kA$ or $1/hA$). Convection and end layers use $A=3\ \mathrm{m^2}$; B and C use $1.5\ \mathrm{m^2}$: $$R_{c1}=\tfrac{1}{50\cdot3}=6.67\times10^{-3},\;R_A=\tfrac{0.05}{50\cdot3}=3.33\times10^{-4},\;R_D=3.33\times10^{-4},\;R_{c2}=\tfrac{1}{10\cdot3}=3.33\times10^{-2}\ \mathrm{K/W}.$$
  2. Parallel middle layer. $R_B=\tfrac{0.10}{10\cdot1.5}=6.67\times10^{-3}$, $R_C=\tfrac{0.10}{1\cdot1.5}=6.67\times10^{-2}$, so $$R_{BC}=\left(\frac{1}{R_B}+\frac{1}{R_C}\right)^{-1}=\frac{1}{150+15}=6.06\times10^{-3}\ \mathrm{K/W}.$$
  3. (b) Total resistance and heat rate. $$R_{\text{tot}}=R_{c1}+R_A+R_{BC}+R_D+R_{c2}=4.673\times10^{-2}\ \mathrm{K/W},$$ $$q=\frac{T_{\infty,1}-T_{\infty,2}}{R_{\text{tot}}}=\frac{200-25}{0.04673}=\boxed{3745\ \mathrm{W}}\ \text{(per metre of depth)}.$$
  4. Interface temperatures. Walk from the hot side: $T_1=T_{\infty,1}-q(R_{c1}+R_A)$ and $T_2=T_1-qR_{BC}$: $$T_1=200-3745(0.00700)=\boxed{173.8,{}^ rc\mathrm{C}},\qquad T_2=173.8-3745(0.006061)=\boxed{151.1,{}^ rc\mathrm{C}}.$$ Checking from the cold side, $25+3745(R_D+R_{c2})=151.1,{}^ rc$C — consistent.
  5. (c) Equivalent single C-layer. Every resistance except the middle is unchanged, so for the same $q$ the middle resistance must equal $R_{BC}=6.06\times10^{-3}$. With C alone spanning the full area (3 m$^2$): $$L_C=R_{BC}\,k_C A=6.06\times10^{-3}(1)(3)=\boxed{18.2\ \mathrm{mm}}.$$
QuantityResult
Total resistance $R_{\text{tot}}$$0.0467\ \mathrm{K/W}$
(b) Heat rate $q$3745 W per m depth (3.75 kW/m)
(b) Interface $T_1$ / $T_2$173.8 / 151.1 °C
(c) Equivalent C thickness18.2 mm