23-Chem-A3 Heat and Mass Transfer · May 2013
Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
National Exams — May 2013 — 04-Chem-A3 Mass Transfer Operations. Three-hour, open-book exam; any non-communicating calculator permitted. Format: seven questions in three parts — answer one of Q1–Q2 (Part A), one of Q3–Q4 (Part B) and two of Q5–Q7 (Part C); four questions constitute a complete paper (Parts A/B carry 20% each, Part C 30% each). All seven are solved below for completeness. Property data are stated in each Given block. Two chart appendices (SI humidity–temperature charts) accompany Q6.
Reference texts: Geankoplis, Transport Processes and Separation Process Principles (4th ed., Prentice Hall) — molecular diffusion, mass-transfer coefficients, absorption, humidification; Welty, Wicks, Wilson & Rorrer, Fundamentals of Momentum, Heat and Mass Transfer (5th/6th ed., Wiley) — transient diffusion, boundary-layer mass transfer; Treybal, Mass-Transfer Operations (3rd ed., McGraw-Hill) — packed-tower and cooling-tower design; supporting data from Perry's Chemical Engineers' Handbook (9th ed.) and Incropera & DeWitt, Fundamentals of Heat and Mass Transfer.
Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.
Given (a). $L=5000$ kg/s water, $310\to296$ K (range 14 K, approach 13 K to the 283 K wet bulb); dry bulb 288 K; performance coefficient $C_t=5.2$, read as the required $K_aV/L$.
Given (b). $L=1000$ kg/s water $40\to30\,°\text{C}$; air in $40\,°\text{C}$, 1.0 bar, 30% RH; air out $35\,°\text{C}$, 70% RH.
Find. (a) the tower base diameter and height; (b)(i) the air mass flow rate and (ii) the make-up water rate.
Approach. Part (a): treat $C_t=5.2$ as the required tower characteristic $K_aV/L$, find the operating $L/G$ that makes the Merkel enthalpy integral equal to it, hence the air rate, then size the plan area and height from a design water loading and aspect ratio. Part (b): humid-air mass and energy balances between the two measured air states.
| Quantity | Result |
|---|---|
| (a) Operating $L/G$ (for $K_aV/L=5.2$) | 1.85 |
| (a) Air rate / base diameter / height | $\approx2.7\times10^{3}$ kg/s · $\approx60$ m · $\approx90$ m |
| (b)(i) Air flow (dry) | $\approx1.85\times10^{3}$ kg/s |
| (b)(ii) Make-up water | $\approx21$ kg/s |
Check: the natural-draft dimensions in (a) are engineering estimates — the base diameter follows from an assumed $1.8\ \text{kg}/(\text{m}^2\cdot\text{s})$ plan-area water loading and the height from a 1.5 aspect ratio (both typical of large hyperbolic towers). The air rate is fixed once $C_t=5.2$ is read as the required $K_aV/L$. Coulson & Richardson Vol. 1 (the source of this paper's humidity-chart appendices) sizes natural-draft towers from a performance-coefficient chart for water loading and height; that chart is not reproduced with the exam, so the loading and aspect ratio above are stated assumptions and the two dimensions should be read as order-of-magnitude estimates. Part (b) is a closed balance and is not assumption-sensitive.