Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
Notes on this paper
National Exam 04-Chem-B10, Life Cycle Assessment (LCA) — May 2016. 3 hours, Closed-Book
Exam (approved calculator and one double-sided aid sheet permitted). Question 1 is mandatory (28
marks); any three (3) of the remaining four (Questions 2–5) constitute a complete 100-mark paper,
and only the first four questions as they appear in the answer book are marked. All five questions are
solved below for completeness.
Reference texts: Baumann & Tillman, The Hitch Hiker's Guide to LCA;
Graedel & Allenby, Industrial Ecology and Sustainable Engineering; Kemp, Pinch
Analysis and Process Integration, 2nd ed.; Mackay, Multimedia Environmental Models: The
Fugacity Approach, 2nd ed.; Davis & Cornwell, Introduction to Environmental
Engineering.
Find. (a) Utility type and flow rate per stream with no integration. (b) Pinch
temperature and minimum hot/cold utility duties via the problem-table (temperature-interval) method.
(c) A feasible heat exchanger network achieving those minimum utility targets.
Approach. Compute each stream's duty CP·ΔT; without integration each
stream is served by whichever utility is both hot/cold enough and cheapest, sized by Q =
ẓ·ΔH. With integration, shift hot streams down and cold streams up by
ΔTmin/2, tabulate the net CP imbalance in each temperature interval between consecutive
shifted stream temperatures, cascade the heat downward from zero at the top, and add the minimum heat
needed at the top to make every cascade value ≥0 — the point where the cascade first reaches
exactly zero is the pinch. A network is then built stream-by-stream honouring the pinch-matching
feasibility rule (CPhot ≤ CPcold for any match touching the pinch from above).
(a) Utility duties without heat integration. Each stream's total duty:
$$Q_{H101}=20.0\times(190-50)=2800\ \text{kW},\quad Q_{C102}=27.0\times(165-95)=1890\ \text{kW},\quad
Q_{C103}=28.0\times(135-50)=2380\ \text{kW}$$
C102's target (165°C) exceeds the practical ceiling of LPS (≈160°C condensing — too
close to 165°C to leave a 10°C approach), so it must be served by HPS; C103's
target (135°C) is comfortably below LPS's ceiling, so the cheaper LPS serves it;
H101 needs only sensible cooling well within the CW range, so CW serves it. Sizing each
from ẓ = Q/|ΔH|:
$$\dot m_{HPS}=\frac{1890}{1700}=\boxed{1.112\ \text{kg/s}},\qquad
\dot m_{LPS}=\frac{2380}{2000}=\boxed{1.190\ \text{kg/s}},\qquad
\dot m_{CW}=\frac{2800}{63}=\boxed{44.44\ \text{kg/s}}$$
(b) Shifted temperatures and the problem-table cascade. Shift the cold streams up
5°C and the hot stream down 5°C (half of ΔTmin) onto a common scale: H101*:
185→45°C; C102*: 100→170°C; C103*: 55→140°C. The six distinct shifted
temperatures (185, 170, 140, 100, 55, 45) bound five internal intervals; in each interval, net =
(ΣCPhot − ΣCPcold)×ΔT of the streams spanning it:
$$[185,170]:\ (20-0)(15)=+300 \quad [170,140]:\ (20-27)(30)=-210 \quad [140,100]:\ (20-55)(40)=-1400$$
$$[100,55]:\ (20-28)(45)=-360 \quad [55,45]:\ (20-0)(10)=+200$$
Cascading from Q=0 at the top gives running totals 0, 300, 90, −1310, −1670, −1470
— the most negative value is −1670 kW, so adding QH,min = 1670 kW
at the top makes every value ≥0. The re-cascaded values are 1670, 1970, 1760, 360,
0, 200 — the cascade hits exactly zero at shifted T*=55°C, which is the pinch
(actual hot-stream pinch temperature 60°C, actual cold-stream pinch temperature 50°C), and the
final value, QC,min = 200 kW, is the minimum cold utility.
$$Q_{H,min}=\boxed{1670\ \text{kW (above pinch)}}\qquad Q_{C,min}=\boxed{200\ \text{kW (below pinch)}}$$
Energy-balance check. Total process heating demand minus total cooling demand
(1890+2380−2800 = 1470 kW) must equal QH,min−QC,min =
1670−200 = 1470 kW — confirmed. Heat integration recovers 2600 kW of process-to-process
exchange (versus 4270+2800 = 7070 kW of total utility duty with no integration at all), a 73.6%
reduction in total utility load.
Fig. 1 — Temperature-interval (problem-table) cascade. The cascade first
touches zero at shifted T*=55°C (actual pinch 60°C hot / 50°C cold), fixing
QH,min=1670 kW and QC,min=200 kW.
(c) Heat exchanger network design. Above the pinch there is one hot stream (H101,
CP=20) and two cold streams (C102, CP=27; C103, CP=28); since Nhot (1) ≤ Ncold
(2) above the pinch, no stream split is required — a single hot stream may simply serve both cold
streams in series. C103's cold inlet (50°C) sits exactly at the cold-pinch temperature, so it forms
the pinch match (the pinch-design "tick-off" heuristic starts here): running H101 down from the pinch
(60°C) while heating C103 fully from 50 to 135°C uses
$$Q_{E2}=28\times(135-50)=2380\ \text{kW}\ \Rightarrow\ H101: 179^\circ\text{C}\rightarrow60^\circ\text{C}$$
which fully satisfies C103 (no utility needed for this stream) and is feasible throughout (10°C
approach at the pinch end, 44°C at the top end — both ≥ΔTmin). The
remaining H101 capacity above the pinch (190→179°C) is then matched against the hot end of
C102:
$$Q_{E1}=20\times(190-179)=220\ \text{kW}\ \Rightarrow\ C102: 156.85^\circ\text{C}\rightarrow165^\circ\text{C}$$
(feasible: 25°C approach at the hot end, 22.15°C at the cold end). C102's remaining duty down to
its 95°C supply,
$$Q_{E3}=1890-220=\boxed{1670\ \text{kW}}=Q_{H,min},$$
must be supplied by HPS: the heater has to deliver C102 at 156.85°C, which with a 10°C approach needs steam condensing at ≥166.85°C — above LPS's 160°C — confirming the same
QH,min found by the cascade. Below the pinch, only H101 remains (60→50°C), cooled by
CW:
$$Q_{E4}=20\times(60-50)=\boxed{200\ \text{kW}}=Q_{C,min}$$
Utility flow rates for the integrated network: $\dot m_{HPS}=1670/1700=\boxed{0.982\ \text{kg/s}}$,
$\dot m_{CW}=200/63=\boxed{3.17\ \text{kg/s}}$. This 4-exchanger network (E1, E2, E3-heater, E4-cooler)
achieves both minimum utility targets exactly, with no LPS required at all in the integrated
design.
Fig. 2 — Grid diagram of the integrated heat exchanger network. H101 (top,
flowing right) is cooled sequentially by E1 (against C102) then E2 (the pinch match, against C103,
green) before continuing below the pinch to a CW trim cooler E4; C102 (flowing left from its 95°C supply) is heated first by the HPS heater E3 and then finished to 165°C by E1, all
above the pinch.