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23-Chem-B2 Environmental Engineering · Undated paper

Question 2 of 7: Control Methods for Particulates, Gases and Vapours

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Notes on this paper

National Exam 16-Chem-B2, Environmental Engineering — May 2019. 3 hours, Closed-Book Exam with a candidate-prepared 8½×11" double-sided aid sheet. Any five (5) of the seven questions constitute a complete paper (100 marks); all seven are solved below for completeness.

Reference texts: Metcalf & Eddy (Tchobanoglous, Burton, Stensel), Wastewater Engineering: Treatment and Reuse, 4th ed.; Davis & Cornwell, Introduction to Environmental Engineering, 5th ed.; Turner, Workbook of Atmospheric Dispersion Estimates, 2nd ed.; Cooper & Alley, Air Pollution Control: A Design Approach, 4th ed.

Problem 2: Control Methods for Particulates, Gases and Vapours (20 marks)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

TechnologyMain principleAdvantagesLimitationsApplication
(i) Electrostatic precipitator (particulates) Dust-laden gas passes between charged discharge electrodes and grounded collection plates; particles acquire a negative charge via corona discharge, migrate under the electric field, and are collected on the plates before being periodically rapped off into a hopper. 1) Very high collection efficiency (often >99%) for PM₂₀ and much finer particulates (PM₁₀, PM₂.₅), unlike purely inertial devices. 2) Low pressure drop (low fan energy cost) compared to a high-efficiency fabric filter for the same gas volume. 1) Efficiency is sensitive to particle resistivity — very high- or very low-resistivity dust (e.g. after a fuel or process change) can sharply reduce collection. 2) High capital cost and a large footprint, plus efficiency degrades quickly if plate rapping/cleaning is neglected (dust re-entrainment). Coal-fired boiler or cement-kiln flue gas, where a large, fairly steady particulate load must be removed at high efficiency with low pressure drop.
(ii) Air (wet) scrubber (gases) The gas stream is contacted with a liquid (usually an alkaline scrubbing solution for an acid gas like SO₂) in a packed or spray tower; the pollutant gas is absorbed into the liquid phase and reacts chemically (e.g. SO₂ with lime/limestone slurry to form gypsum), removing it from the gas stream. 1) High removal efficiency for soluble/reactive acid gases such as SO₂ (often >90–95% with a well-designed wet limestone system). 2) Can simultaneously knock down some particulate matter and cool the gas stream. 1) Generates a wet waste/byproduct stream (scrubber liquor or gypsum sludge) requiring further handling or disposal, an added carbon/cost burden. 2) High pressure drop and pumping/reagent energy demand relative to a dry control technology. Coal- or oil-fired utility boiler SO₂ control (wet flue-gas desulfurization), or acid-gas control on a smelter or chemical-process off-gas.
(iii) Adsorption (odorous vapours/VOCs) The vapour stream is passed through a bed of activated carbon (or other high-surface-area sorbent); VOC molecules are physically adsorbed onto the internal pore surface until the bed approaches saturation (breakthrough), at which point it is replaced or thermally regenerated. 1) Very high removal efficiency for a wide range of non-polar organic vapours, including many odorous compounds not easily biodegraded. 2) Compact, simple, low-energy operation for a dilute, intermittent vapour stream. 1) Capacity is limited and humidity/competing-compound sensitive; a saturated bed breaks through and stops removing the target compound without warning unless outlet monitoring is in place. 2) Spent carbon is a waste stream requiring regeneration or disposal, and regeneration (steam or thermal) is itself an energy cost. Solvent-recovery, tank-farm vent, or odour-control polishing stage handling a dilute, intermittent VOC or odorous-vapour stream downstream of a primary control device.

The three technologies target different phases and particle/molecule size ranges: the ESP is a physical particulate collector whose efficiency depends on electrostatic charging rather than particle inertia (so it remains highly efficient down to sub-micron particulates, unlike a cyclone), the wet scrubber removes gas-phase pollutants by mass transfer into a reactive liquid (so its performance hinges on gas solubility/reactivity, not particle size at all), and carbon adsorption removes vapour-phase organics by physical sorption onto a solid surface, making it well suited to compounds too dilute or non-biodegradable for a scrubber or biofilter. Selecting among them (or combining them in series, e.g. ESP upstream of a wet scrubber) is therefore driven first by contaminant phase and chemistry, and only secondarily by capital/operating cost.