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18-Env-A4 Water and Wastewater Engineering · December 2015

Question 2 of 5: Disinfection and Water Treatment Unit Processes

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

National Exams — December 2015 — 04-Env-A4 / Water and Wastewater Engineering. 3 hours duration; closed book with one double-sided aid sheet; approved calculator permitted. Question 1 is compulsory; the paper instructs candidates to attempt any three of the remaining four (100 marks total); all five are solved below for completeness. (The source page prints an internal header inconsistency — "NATIONAL EXAMINATION, MAY 2015" beside a page footer reading "December 2015" — the period is taken as December 2015 per the footer; this does not affect any question content.)

Reference texts. Metcalf & Eddy, Wastewater Engineering: Treatment and Resource Recovery; Davis & Cornwell, Introduction to Environmental Engineering; MWH's Water Treatment: Principles and Design; Guidelines for Canadian Drinking Water Quality (Health Canada).

Question 2: Disinfection and Water Treatment Unit Processes (25 marks)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

a. UV Disinfection — Principle, Advantages and Disadvantages (10 marks)

UV disinfection passes water through a reactor chamber where lamps — low-pressure mercury-vapour (near-monochromatic, peak germicidal output around 254 nm) or medium-pressure (polychromatic) — emit ultraviolet light that is absorbed directly by microbial nucleic acids (DNA/RNA). The absorbed photons form pyrimidine dimers, most commonly thymine dimers, which physically block replication and transcription; the organism is thereby inactivated — genetically disabled from reproducing — without any chemical reaction, additive or residual. Reactors are validated by bioassay and sized to deliver a required UV dose (intensity × exposure time, mJ/cm²) that meets a target log-inactivation credit (e.g., 3-log Giardia, 4-log virus under the multi-barrier treatment goals in the Guidelines for Canadian Drinking Water Quality).

Advantages over chlorination: no chlorinated disinfection by-products (THMs/HAAs) are formed, since there is no chemical reaction with natural organic matter; UV is highly effective against chlorine-resistant protozoan (oo)cysts — Cryptosporidium and Giardia — at achievable, practical doses, where chlorine is essentially ineffective; there is no chemical storage, handling or transport hazard; contact time is measured in seconds rather than minutes; and UV does not alter taste or odour. Disadvantages: UV leaves no residual disinfectant, so it provides no protection against regrowth or recontamination in the distribution system and a secondary chemical disinfectant (chlorine/chloramine) is normally still required downstream; performance depends strongly on water quality, since turbidity and particulates shield organisms from exposure, and some organisms can partially reverse UV damage through photoreactivation or dark repair; lamps require periodic cleaning (fouling reduces UV transmittance) and replacement; capital cost and continuous electrical dependency are higher, with no disinfection at all during a power outage unless backed up; and performance cannot be confirmed with a simple field residual test, relying instead on continuously monitored UV-intensity sensors and validated flow.

b. Coagulation, Flocculation, Filtration, Adsorption and Ion Exchange (15 marks)

Coagulation adds a chemical coagulant (alum, ferric chloride, or a cationic polymer) that neutralizes the negative surface charge on colloidal particles (clay, natural organic matter, some pathogens) and/or forms metal-hydroxide precipitates that physically sweep particles from suspension, destabilizing them so they can aggregate. It is necessary whenever a source carries fine colloidal turbidity or colour that will not settle on its own — a surface-water intake during a high-turbidity runoff event, or an algae-laden reservoir.

Flocculation is gentle, prolonged mixing (a tapered, decreasing velocity gradient $G$) applied immediately after coagulation, bringing destabilized particles into physical contact so they collide and build into larger, readily-settleable flocs. It is necessary any time a coagulant has just been dosed, because charge neutralization alone does not make particles aggregate — they must actually collide, which is what flocculation's controlled mixing provides.

Filtration passes water through a granular media bed (single-medium sand, or dual-media sand-over-anthracite) that removes remaining particulate matter by straining, sedimentation within the pore spaces, and interception/adsorption onto the grain surfaces. It is necessary as a polishing step downstream of clarification (or as direct filtration where raw turbidity is already low) to meet turbidity/particle-removal targets and to provide a physical barrier against Cryptosporidium and Giardia that survive coagulation-sedimentation.

Adsorption removes dissolved organic contaminants — taste-and-odour compounds such as geosmin and 2-methylisoborneol from algal blooms, natural organic matter that would otherwise drive high disinfection-by-product formation, and specific trace organics or pesticides — onto the high-surface-area micropores of activated carbon, either as a granular contactor or as powdered carbon dosed ahead of filtration. It is necessary whenever conventional coagulation/filtration alone cannot remove a dissolved organic problem, such as a seasonal taste-and-odour episode or elevated DOC.

Ion exchange replaces a dissolved ionic species with a less-objectionable ion held on a resin bed — classically Ca²⁺/Mg²⁺ exchanged for Na⁺ in water softening, or nitrate, arsenate and similar anions exchanged on an anion resin. It is necessary for hardness removal from a groundwater supply, or for targeted removal of a specific dissolved ion (nitrate in agricultural groundwater, arsenic, uranium) that physical clarification and filtration do not touch at all, since these are true dissolved-ion problems rather than particulate ones.