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18-Env-B7 Environmental Sampling and Analysis · December 2016

Question 2 of 6: Paired T-Test for Two SO₂ Measurement Times

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

National Exams — December 2016 — 04-Env-B7 / Environmental Sampling and Analysis. 3 hours duration; closed book (approved non-programmable Sharp or Casio calculator only); t-distribution table supplied. Part A (Questions 1–3) is compulsory; Part B (Questions 4–6, "answer any 2") – all three are solved below for completeness.

Reference texts. Walpole, Myers, Myers & Ye, Probability & Statistics for Engineers and Scientists (statistical hypothesis testing, exploratory data analysis); Davis & Cornwell, Introduction to Environmental Engineering (6th ed.) (sampling design, QA/QC, environmental monitoring programs); U.S. EPA Guidance for Choosing a Sampling Design for Environmental Data Collection (QA/G-5S); Canadian Council of Ministers of the Environment (CCME) monitoring and reporting guidance.

Question 2: Paired T-Test for Two SO₂ Measurement Times (20 marks)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

Check: the exam's own scenario sentence names a 10% significance level, while part (a) explicitly instructs "at the 5% significance level" – these are two different numbers stated for the same test. Part (a) is solved literally at the instructed 5% level below; the 10% figure is also checked in Step 4 for completeness (the conclusion is identical at both levels, so the discrepancy does not change the answer).

(a) Which Test, and the Conclusion

Given.

10 paired locations, and the differences $d_i=T1_i-T2_i$ (ppm SO₂)
LocationTime 1Time 2$d_i=T1_i-T2_i$
168.371.8−3.5
266.560.16.4
362.965.2−2.3
464.863.51.3
566.668.5−1.9
669.471.8−2.4
765.262.13.1
862.568.2−5.7
970.465.15.3
1062.268.9−6.7
Mean / StDev65.88 / 2.8966.52 / 3.97−0.64 / 4.48

Find. The appropriate t-procedure, its test statistic, and whether Time 1 is significantly different from Time 2 at $\alpha=0.05$.

Approach. Determine whether the two columns are independent or paired, then apply the matching t-procedure to the 10 differences and compare the statistic to the supplied t-table.

  1. Identify the design. Time 1 and Time 2 were both measured at the same 10 locations in the building – each pair $(T1_i,T2_i)$ shares a common location, so the two columns are naturally correlated rather than independent. The paired t-test is therefore the statistically appropriate procedure: it works directly on the 10 differences $d_i=T1_i-T2_i$, so location-to-location variability common to both readings cancels out of the comparison, leaving only the genuine systematic difference between the two times. An independent two-sample test would ignore that correlation and misstate the standard error of the difference.
  2. Hypotheses. $H_0:\mu_d=0$ (Time 1 is not significantly different from Time 2) vs. $H_a:\mu_d\ne0$ (two-sided, matching the "not significantly different" wording, a statement of equality).
  3. Test statistic. $\bar d=-0.64$, $s_d=4.479$, $SE_{\bar d}=s_d/\sqrt{n}=4.479/\sqrt{10}=1.416$. $$t=\frac{\bar d}{SE_{\bar d}}=\frac{-0.64}{1.416}$$ $$t=\boxed{-0.452}\qquad(df=n-1=9)$$
  4. Critical value and decision. For a two-tailed test at $\alpha=0.05$, each tail carries 0.025; from the supplied t-table at $df=9$, $t_{0.025,9}=2.262$. Since $|t|=0.452<2.262$, we fail to reject $H_0$. (At the scenario sentence's 10% level, $t_{0.05,9}=1.833$ – still $|t|=0.452<1.833$, the same decision.)

Conclusion. At both the instructed 5% level and the scenario's stated 10% level, there is no statistically significant difference between the Time 1 and Time 2 SO₂ readings – the control measures show no detectable shift in pollutant concentration between the two measurement times, which is exactly what the exam scenario set out to demonstrate.

(b) Main Assumption and Graphical Check

The paired t-test's main assumption is that the population of paired differences $d_i=T1_i-T2_i$ is (at least approximately) normally distributed. With only $n=10$ pairs, the Central Limit Theorem cannot be relied on to normalize a non-normal difference distribution on its own, so approximate normality of the $d_i$ themselves is required for the t reference distribution used in part (a) to be valid.

A simple graphical check is a normal probability (quantile-quantile) plot of the 10 sorted differences against their theoretical normal quantiles: if the points fall close to a straight line, normality is a reasonable working assumption; systematic curvature or a lone far-outlying point would instead signal a problem.

Theoretical normal quantileOrdered difference (T1-T2), ppm-101-6-4-20246
Fig. 1 – Normal probability plot of the 10 paired differences $d_i=T1_i-T2_i$ against their theoretical normal quantiles, with a fitted reference line through the sample mean and standard deviation. The points track the line reasonably closely with no severe curvature or isolated outlier, supporting the normality assumption used for the paired t-test in part (a).

(c) Alternative Tests

If the normality of the differences were in doubt (e.g. the Q–Q plot in part (b) had shown clear curvature or a severe outlier), the standard distribution-free alternative to the paired t-test is the Wilcoxon signed-rank test, which ranks the absolute differences $|d_i|$, restores the sign of each rank, and tests whether the signed-rank sum is consistent with a symmetric distribution centred on zero – it uses more information than a simple sign count and is the usual first choice when normality fails but the differences are still reasonably symmetric. A cruder but assumption-free alternative is the sign test, which only counts how many differences are positive versus negative (ignoring magnitude) and compares that count to a binomial(n, 0.5) reference – it is less powerful than the Wilcoxon signed-rank test but requires no distributional assumption at all beyond independence of the pairs. A third option, if the underlying process is believed genuinely independent rather than paired, would be an independent two-sample Welch's t-test (unequal-variance t-test), though that would be the wrong model here given the paired design identified in part (a).

Final results – Question 2
ItemResult
(a) Appropriate testPaired t-test – the 10 locations are the same for both measurement times (correlated, not independent)
(a) Test statistic$t=-0.452$ ($df=9$)
(a) Critical value ($\alpha=0.05$, two-tailed)$t_{0.025,9}=2.262$
(a) Decision / ConclusionFail to reject $H_0$ – Time 1 and Time 2 are not significantly different (at 5% or 10%)
(b) Main assumptionPaired differences $d_i$ are approximately normally distributed
(b) Graphical checkNormal probability plot of $d_i$ – points track the reference line, no severe departure
(c) AlternativesWilcoxon signed-rank test; sign test