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21-Mat-A1 Thermodynamics: May 2017

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

  1. Question 1 First-Law Bookkeeping Around a Rectangular P–V Cycle
  2. Question 2 Entropy of Reversible vs. Irreversible Isothermal Compression
  3. Question 3 Reaction Entropy of Ammonia Synthesis at 700 K
  4. Question 4 Thermodynamics of Sulfuric Acid Formation from Elemental Sulfur
  5. Question 5 Heats of Combustion and Gravimetric Energy Density of Four Fuels
  6. Question 6 Galvanic Cell Thermodynamics for Ba/Cu 2+
  7. Question 7 Ellingham-Diagram Equilibria for Si/SiO₂ and the Ti–SiO₂ Reduction

Start with Question 1 →

National Exams — May 2017 — 10-Met-A1 Metallurgical Thermodynamics. Three-hour, closed-book exam using an approved (Casio or Sharp) calculator; candidates were told to state any interpretive assumptions. Any five of the seven questions constitute a complete paper — all seven are solved below for completeness. All questions are of equal value (20 marks each out of 100).

Reference texts: Gaskell, D. R., Introduction to the Thermodynamics of Materials (2nd–5th ed.) — source of the first-law/second-law relations used throughout and of the attached Ellingham diagram (Fig. 9-3) and its underlying 298 K formation data used in Question 7; supporting 298 K entropies for CO(g), CO₂(g), H₂(g) and H₂O(g) from the NIST–JANAF Thermochemical Tables.