NivaarExam PrepOfficial exam papers ↗

21-Mat-A2 Materials Transport Phenomena · May 2017

Question 3 of 5: Radiative/Convective Solidification of a Casting Top Layer

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

National Exams — May 2017 — 12-MTL-A2 Transport Phenomena in Materials Engineering. Three-hour, open-book exam (one textbook of the candidate's choice permitted, no loose notes); any non-communicating calculator permitted. Each of the five questions is worth 25 points, and any four constitute a complete paper — only the first four questions as they appear in the answer book are marked. All five are solved below for completeness. Candidates were told to state all assumptions clearly.

Reference texts: Welty, J. R., Wicks, C. E., Wilson, R. E. & Rorrer, G. L., Fundamentals of Momentum, Heat and Mass Transfer — pipe-friction/Moody-chart methodology (Question 1) and differential-balance derivations (Question 5); Levenspiel, O., Chemical Reaction Engineering — residence-time-distribution moments and the tanks-in-series model (Question 2); Geiger, G. H. & Poirier, D. R., Transport Phenomena in Materials Processing — radiative/convective solidification analysis and the Wiedemann–Franz–Lorenz relation (Question 3); Incropera, F. P. et al., Fundamentals of Heat and Mass Transfer — Biot number and lumped-capacitance criteria (Question 3); Ashby, M. F., Materials Selection in Mechanical Design — thermal-property material-selection charts (Question 4); Geankoplis, C. J., Transport Processes and Separation Process Principles — steady-state Fickian diffusion through a cylindrical tube wall (Question 5).

Question 3: Radiative/Convective Solidification of a Casting Top Layer (25 marks: (a) 3, (b) 2.5, (c) 3.5, (d) 4, (e) 6, (f) 6)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

Given.

QuantitySymbolValue
Electrical conductivity of iron near $T_m$$\sigma_e$$5\times10^5\ (\Omega\cdot\text{m})^{-1}$
Density$\rho$$7500\ \text{kg/m}^3$
Heat capacity$c_p$$500\ \text{J/kg}\cdot\text{K}$
Melting point$T_m$$1800\ \text{K}$
Heat of fusion$\Delta H_f$$267\ \text{kJ/kg}$
Radiative emissivity of solidified-layer top$\varepsilon$0.6
Convective coefficient to air$h$$100\ \text{W/m}^2\cdot\text{K}$

Find. (a) $k_{Fe}$; (b) the flux expression; (c) $h_{total}$; (d) the solidified-layer thickness $Y$ where $Bi=0.1$; (e) $dY/dt$ under a uniform-temperature (Biot $\ll0.1$) layer; (f) the governing (unsolved) equation once conduction through the shell also matters.

moldliquid metal (T = T_m, uniform)solid layer, thickness Y(t)q = h(T_s−T∞) + εσ(T_s⁴−T∞⁴) → environment (black, T∞ << T_s)Y
Fig. 3 — solid layer of thickness $Y(t)$ growing downward from the top of the ingot, losing heat to the environment by combined radiation and convection.

Approach. (a) uses the Wiedemann–Franz–Lorenz law to convert the given electrical conductivity to a thermal conductivity, since no $k$ value is supplied directly; (b)–(c) linearize the combined radiative/convective boundary condition into a single surface coefficient; (d) applies the standard lumped-capacitance Biot criterion; (e) is an interface energy balance (latent heat released = heat lost from the top) valid while the layer itself is isothermal; (f) restates that same interface balance once the layer's own conduction resistance can no longer be neglected.

  1. (a) Thermal conductivity via Wiedemann–Franz–Lorenz. For a free-electron conductor, $k=L_0\sigma_eT$ with Lorenz number $L_0=2.44\times10^{-8}\ \text{W}\cdot\Omega/\text{K}^2$: $$k=L_0\sigma_eT_m=(2.44\times10^{-8})(5\times10^5)(1800)=\boxed{22.0\ \text{W/m}\cdot\text{K}}$$ consistent with handbook values for iron near its melting point.
  2. (b) Combined flux expression. With the environment black and the layer top grey (view factor 1, no reflected radiation returning), the net radiative flux is $\varepsilon\sigma_{SB}(T_s^4-T_\infty^4)$; adding Newton's-law convection: $$q=h(T_s-T_\infty)+\varepsilon\sigma_{SB}\left(T_s^4-T_\infty^4\right)$$
  3. (c) Total heat transfer coefficient. With $T_\infty\ll T_s$, drop $T_\infty$ terms and factor out $T_s$: $q\approx h\,T_s+\varepsilon\sigma_{SB}T_s^4=T_s\big(h+\varepsilon\sigma_{SB}T_s^3\big)=h_{total}T_s$, evaluated at the layer-top temperature $T_s=T_m=1800$ K: $$h_{total}=h+\varepsilon\sigma_{SB}T_m^3=100+0.6(5.67\times10^{-8})(1800)^3=100+198.4=\boxed{298.4\ \text{W/m}^2\cdot\text{K}}$$
  4. (d) Solidified-layer thickness at $Bi=0.1$. $Bi=h_{total}Y/k_{Fe}$: $$Y=\frac{Bi\cdot k_{Fe}}{h_{total}}=\frac{0.1(22.0)}{298.4}=\boxed{7.4\ \text{mm}}$$ Below this thickness the uniform-layer-temperature assumption of part (e) is valid; above it, conduction resistance in the layer (part f) becomes significant.
  5. (e) Growth rate, uniform-layer limit. With the layer isothermal at $T_s=T_m$, the heat leaving the top, $q=h_{total}T_m$, must equal the rate of latent heat released as the solidification front advances (quasi-steady, no accumulation in the thin layer): $$\rho\,\Delta H_f\frac{dY}{dt}=h_{total}T_m\;\Rightarrow\;\frac{dY}{dt}=\frac{h_{total}T_m}{\rho\,\Delta H_f}=\frac{298.4(1800)}{7500(267{,}000)}=\boxed{2.68\times10^{-4}\ \text{m/s}\ (=0.268\ \text{mm/s})}$$
  6. (f) Combined conduction + surface-loss equation (not solved). Once the solidified layer is thick enough that its own conduction resistance matters, the top surface temperature $T_s$ is no longer $T_m$; it is set by requiring the conductive flux through the layer to match the flux leaving the top surface, and the interface energy balance uses that same flux: $$\frac{k_{Fe}\left(T_m-T_s\right)}{Y}=h\left(T_s-T_\infty\right)+\varepsilon\sigma_{SB}\left(T_s^4-T_\infty^4\right)\qquad\text{(surface-flux match, implicitly defines }T_s(Y)\text{)}$$ $$\rho\,\Delta H_f\frac{dY}{dt}=\frac{k_{Fe}\left(T_m-T_s\right)}{Y}\qquad\text{(interface energy balance)}$$ These two coupled, nonlinear equations in $Y(t)$ and $T_s(t)$ define the growth law; they are not solved here, per the question's instruction.
QuantityValue
Thermal conductivity, $k_{Fe}$22.0 W/m·K
Combined flux expression$q=h(T_s-T_\infty)+\varepsilon\sigma_{SB}(T_s^4-T_\infty^4)$
Total heat transfer coefficient, $h_{total}$298.4 W/m²·K
Solidified-layer thickness at $Bi=0.1$, $Y$7.4 mm
Growth rate (uniform-layer limit), $dY/dt$$2.68\times10^{-4}$ m/s
Combined-limit growth lawset up in step 6 (not solved)
Check
The Wiedemann–Franz estimate in (a) applies the free-electron law at $T_m$, which is standard practice for estimating a metal's thermal conductivity when only electrical conductivity data is supplied, but is an approximation (real iron near $T_m$ deviates somewhat from the ideal free-electron value). Parts (c)–(e) evaluate $h_{total}$ and $q$ at $T_s=T_m$, consistent with the layer being isothermal in that regime; this is no longer valid once the layer thickens past the $Bi=0.1$ threshold found in (d), which is exactly the regime part (f) addresses.