21-Mat-B10 Properties and Processing of Micro- and Nanomaterials · December 2018
Question 3 of 6: Photon Emission in In-Doped Silicon and an Alumina Multilayer Capacitor
Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
Notes on this paper
National Exams — 12-Mtl-B10, Advanced Electronic Materials — December 2018, 3 hours. Six questions; Question 6 (40 marks) is mandatory and any 4 of the remaining 5 questions (15 marks each) complete the paper. All six are answered below.
Reference texts: S.O. Kasap, Principles of Electronic Materials and Devices; W.D. Callister, Materials Science and Engineering: An Introduction.
Question 3: Photon Emission in In-Doped Silicon and an Alumina Multilayer Capacitor (15 marks)
3.1 — Photon wavelengths from the In acceptor level in Si
Given. Silicon bandgap Eg = 1.07 eV; indium acceptor level (above the valence band) Ea = 0.16 eV; Planck's constant h = 4.136×10-15 eV·s; speed of light c = 3×1010 cm/s.
Find. The wavelength of the photon emitted when an electron (a) drops from the conduction band to the acceptor band, and (b) drops from the acceptor band to the valence band.
Approach. Each transition's photon energy is the corresponding energy gap; convert to wavelength with λ = hc/E.
(a) Conduction band → acceptor band. This transition spans the gap minus the acceptor level:
$$E_{(a)}=E_g-E_a=1.07-0.16=0.91\ \text{eV}$$
$$\lambda_{(a)}=\dfrac{hc}{E_{(a)}}=\dfrac{(4.136\times10^{-15})(3\times10^{10})}{0.91}=1.364\times10^{-4}\ \text{cm}=\boxed{1364\ \text{nm}}\ \ (\text{near-infrared})$$
(b) Acceptor band → valence band. This transition spans only the acceptor level itself:
$$\lambda_{(b)}=\dfrac{hc}{E_a}=\dfrac{(4.136\times10^{-15})(3\times10^{10})}{0.16}=7.755\times10^{-4}\ \text{cm}=\boxed{7755\ \text{nm}\ (7.76\ \mu\text{m})}\ \ (\text{mid-infrared})$$
3.2 — Alumina multilayer capacitor sizing
Given. Sheet dimensions 1.5 cm × 1.5 cm × 0.001 cm; K = 6.5; ε0 = 8.85×10-14 F/cm; target capacitance C = 0.0142 µF.
Find. The number of sheets N needed.
Approach. A multilayer capacitor stacks sheets between alternating electrodes, so each sheet forms its own parallel-plate capacitor and the stack behaves as N identical capacitors connected in parallel: Ctotal = N·C1.
Single-sheet capacitance. Sheet area A = 1.5 × 1.5 = 2.25 cm², thickness d = 0.001 cm:
$$C_1=\dfrac{\varepsilon_0 K A}{d}=\dfrac{(8.85\times10^{-14})(6.5)(2.25)}{0.001}=1.294\times10^{-9}\ \text{F}=1.294\ \text{nF}$$
Sheets required.
$$N=\dfrac{C}{C_1}=\dfrac{1.42\times10^{-8}}{1.294\times10^{-9}}=10.97\ \Rightarrow\ \boxed{N=11\ \text{sheets}}$$
(rounded up, since a fractional sheet cannot be built and 10 sheets would fall short of the target).