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24-Pet-A1 Principles of Stratigraphy and Sedimentation · May 2013

Question 13 of 15: Petroleum Source Rocks – Features, Origin and Burial Evolution

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Notes on this paper

EGBC National Exam — Petroleum Engineering, 98-Pet-A1 Principles of Stratigraphy & Sedimentation, 2013-May. 3 hours duration; closed book, no calculator permitted. Candidates answer any 10 of the 15 questions (10 marks each, 100 marks total) and are asked to illustrate answers with drawings wherever possible.

Reference texts: Boggs, S. Jr., Principles of Sedimentology and Stratigraphy, 5th ed., Pearson (texture classification, evaporites, clay minerals, sediment gravity flows, storm/shelf processes, bedforms, stable isotopes, geological time scale); Tucker, M.E., Sedimentary Petrology, 3rd ed., Blackwell (carbonate fabric, dolomitization, reef facies); Nichols, G., Sedimentology and Stratigraphy, 2nd ed., Wiley-Blackwell (depositional systems, transgression/regression, sequence stratigraphy); Reading, H.G. (ed.), Sedimentary Environments: Processes, Facies and Stratigraphy, 3rd ed., Blackwell (facies models); Selley, R.C. & Sonnenberg, S., Elements of Petroleum Geology, 3rd ed., Academic Press (source rock maturation, petroleum systems); International Commission on Stratigraphy, International Chronostratigraphic Chart (geological time scale).

Question 13: Petroleum Source Rocks – Features, Origin and Burial Evolution (10 marks)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

A petroleum source rock is a fine-grained sedimentary rock (shale, mudstone, or organic-rich marl/limestone) containing enough preserved organic matter to have generated, or be capable of generating, commercial quantities of oil and/or gas on burial and heating.

Distinguishing features

Origin

Organic matter – marine phytoplankton/zooplankton or terrestrial plant debris – is deposited along with fine clastic sediment in a setting combining high biological productivity (to supply enough organic matter) with restricted oxygen circulation and/or rapid burial (to prevent that organic matter being oxidized before it can be preserved) – classic settings include anoxic silled basins, upwelling-driven high-productivity continental margins, and stratified (anoxic bottom-water) lakes.

Kerogen maturation with burialdepth / temperature →Diagenesis<50°C, biological; kerogen formsOil window(catagenesis)≈60–120°C, Ro 0.6–1.3%Gas window(catagenesis)≈120–150°C, wet→dry gasMetagenesis>150°C, dry gas, overmature
Kerogen maturation with progressive burial: diagenesis forms kerogen at shallow depth/low temperature, followed by catagenesis through the oil window then the gas window, and finally metagenesis at the deepest, hottest, overmature stage.

Evolution with burial

As the source rock is progressively buried and heated, its kerogen passes through three stages: diagenesis (shallow, <≈50 °C, biological/low-temperature reactions convert biopolymers into kerogen, generating only minor biogenic methane); catagenesis (roughly 60–150 °C, thermal cracking of kerogen generates first oil, through the oil window ≈60–120 °C, vitrinite reflectance Ro≈0.6–1.3%, then progressively drier gas through the gas window ≈120–150 °C as continued cracking breaks liquid hydrocarbons down further); and metagenesis (>150 °C, only dry methane and ultimately graphitic residue remain – the rock is overmature and can generate no more liquid hydrocarbon).