24-Pet-A2 Petroleum Reservoir Fluids · December 2019
Question 3 of 7: Porosimetry and Undersaturated Oil PVT
Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
Notes on this paper
EGBC National Exam — Petroleum Engineering, 17-Pet-A2 Petroleum Reservoir Fluids, 2019-Dec. 3 hours duration, closed book (ruler and approved calculator only). SEVEN questions are printed on the paper; per the exam notes, FIVE questions constitute a complete exam paper and only the first five as answered are marked. Every question is solved in full below (all seven, not just the five a candidate would normally submit) so this set also serves as complete study material.
Reference texts: McCain, W.D., The Properties of Petroleum Fluids, 3rd ed. (PennWell); Ahmed, T., Reservoir Engineering Handbook, 5th ed.; Craft, B.C. & Hawkins, M.F., Applied Petroleum Reservoir Engineering, 3rd ed.; Standing, M.B., Volumetric and Phase Behavior of Oil Field Hydrocarbon Systems; Danesh, A., PVT and Phase Behaviour of Petroleum Reservoir Fluids.
Check: Questions 2 and 6 are built around two classic published P–T phase-diagram figures (the ethane/n-heptane system of Kay, Ind. Eng. Reading exact bubble/dew/critical points off these charts, as the exam intends, is not possible from this source. Every requested quantity in Q2 and Q6 is instead computed analytically: pseudo-critical properties via Kay's mixing rule (the exam's own formula sheet supplies exactly this rule) and bubble/dew points via the standard Wilson K-value correlation, $K_i = (P_{ci}/P)\exp[5.373(1+\omega_i)(1-T_{ci}/T)]$ — the textbook approximate method for hand/exam flash calculations. This gives fully verifiable, reproducible numbers in place of a chart reading, but they are engineering estimates, not a literal digitization — flagged at each affected step below.
Question 3: Porosimetry and Undersaturated Oil PVT (20 marks)
Approach. The helium/gas space in the sample cell is the cell volume minus the rock's grain (matrix) volume, $V_{cell}-(V_b-V_p)$. Applying Boyle's law before and after opening the valve to the empty reference cell gives one equation in $V_p$.
Set up Boyle's law. Gas-occupied volume before expansion $=V_{cell}-V_b+V_p=7+V_p$; after opening to the reference cell, gas volume $=7+V_p+V_{ref}=15+V_p$. $$P_1(7+V_p)=P_2(15+V_p)$$
(b) $B_o$, $R_s$, $B_g$ for undersaturated oil at 2800 psia, 250°F
Given. $P_i=2800$ psia $> P_b=1800$ psia (undersaturated); $T=250\,{}^{\circ}\text{F}$; reservoir liquid production $=100$ bbl/d; stock-tank oil $=65$ STB/d; combined (separator+stock-tank) gas $=50{,}000$ scf/d; gas gravity $\gamma_g=0.7$.
Find. $B_o$, $R_s$ and $B_g$ at reservoir conditions.
Approach. Because reservoir pressure exceeds the bubble point, all the produced gas was dissolved in the oil at reservoir conditions (no free gas cap in the reservoir), so $B_o$ and $R_s$ follow directly from the produced volumes; $B_g$ uses the real-gas law with $Z$ from the Dranchuk–Abou-Kassem (DAK) correlation applied to the formula sheet's pseudo-critical rules.
Solution GOR. Since $P>P_b$, all produced gas came out of solution at the stock tank, so the total measured GOR equals $R_s$ at reservoir conditions: $$R_s = \frac{50{,}000\text{ scf/d}}{65\text{ STB/d}} = \boxed{769.2\ \text{scf/STB}}$$
Z-factor (DAK correlation) and $B_g$. Solving the DAK implicit equation at $(T_r,P_r)=(1.823,4.185)$: $Z=0.905$. $$B_g = 0.02827\frac{ZT}{p} = 0.02827\times\frac{0.905\times710}{2800} = \boxed{0.00649\ \text{ft}^3/\text{scf}}$$
Quantity
Value
$B_o$
1.5385 bbl/STB
$R_s$
769.2 scf/STB
Z (DAK, reservoir cond.)
0.905
$B_g$
0.00649 ft³/scf
Check: because $P_i>P_b$, no free gas phase actually exists in this reservoir – $B_g$ above is the gas-phase property the produced associated gas would have if evaluated at reservoir $p,T$ (needed e.g. for a two-phase $B_t$ calculation once pressure later falls below $P_b$), not a statement that free gas is currently present downhole.