Question 7 of 7: Casting Solidification Defects; Chvorinov's Rule
Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
Notes on this paper
National Exam 04-BS-11, Properties of Materials — December 2014. 3 hours,
closed-book examination (approved Casio or Sharp calculator only). Any five questions constitute
a complete paper; only the first five questions as they appear in the answer book are marked. All
seven questions are solved below for completeness.
Given. (b) 2 in cube of bronze, $t_s=8.2$ min; a $1\times1\times6$ in bar cast
under similar conditions (same mold/metal, so the same Chvorinov constant $B$ and exponent
$n=2$ apply, per page 1).
Find. (a) The two most common solidification defects and precautions.
(b) Solidification time for the bar.
Approach
Part (a) is conceptual: the two classic solidification defects are shrinkage porosity and gas
porosity. Part (b) applies Chvorinov's rule, $t_s=B(V/A)^n$: since the mold/metal/pouring
conditions are unchanged, the constant $B$ (and $n=2$) found from the cube apply directly to the
bar — only the geometry-dependent volume-to-surface-area ratio changes.
(a) Shrinkage porosity/cavity. Liquid metal occupies more volume than the same
mass of solid; as solidification proceeds inward from the mold walls, the last region to solidify
(often the thermal centre or a hot spot) has no further liquid available to feed it, leaving a
void. Precaution: place risers (feeder heads) at the last-to-solidify location to
supply make-up liquid, promote directional solidification toward the riser (progressively
larger sections, or chills to locally speed solidification elsewhere), and design gating to avoid
isolated hot spots.
Gas porosity. Dissolved gases (e.g. hydrogen in aluminum and copper alloys)
are more soluble in the liquid than in the solid; as the metal solidifies, rejected gas can be
trapped as bubbles within the casting. Precaution: degas the melt before pouring,
use non-turbulent gating/pouring practice to avoid entraining air, and provide adequate mold
venting.
(b) Chvorinov constant from the cube. For the 2 in cube, $V=2^3=8\ \text{in}^3$
and $A=6(2\times2)=24\ \text{in}^2$, so $V/A=1/3=0.3333$ in. With $n=2$ (given, page 1) and
$t_s=8.2$ min,
$$B=\frac{t_s}{(V/A)^2}=\frac{8.2}{(0.3333)^2}=\boxed{73.8\ \text{min/in}^2}.$$
Solidification time for the bar. For the $1\times1\times6$ in bar,
$V=1\times1\times6=6\ \text{in}^3$ and
$A=2(1\times1)+2(1\times6)+2(1\times6)=2+12+12=26\ \text{in}^2$, so $V/A=6/26=0.2308$ in. Applying
the same $B$,
$$t_{s,bar}=B\left(\frac{V}{A}\right)^2=73.8\times(0.2308)^2=\boxed{3.93\ \text{min}}.$$
The bar solidifies more than twice as fast as the cube despite having less than 3/4 of its volume,
because its thinner cross-section gives it much more surface area per unit volume to reject heat
through.