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21-Mat-B10 Properties and Processing of Micro- and Nanomaterials · May 2013

Question 2 of 6: Conduction in Copper — Carrier Fraction, Wire Sizing and Drift Velocity

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

National Exams — 10-Met-B10, Advanced Electronic Materials — May 2013, 3 hours. Six questions; Question 6 (40 marks) is mandatory and any 4 of the remaining 5 questions (15 marks each) complete the paper. All six are answered below.

Reference texts: S.O. Kasap, Principles of Electronic Materials and Devices; W.D. Callister, Materials Science and Engineering: An Introduction.

Two points matter: Question 4 prints the GaAs carrier density per m³ (not per cm³), which sets the conductivity scale; and the formula sheet prints Planck's constant as h = 4.375×10-15 eV·s, which is not the physical value (4.136×10-15 eV·s) — the standard value is used in Question 5.1 and the result with the printed value is also given.

Question 2: Conduction in Copper — Carrier Fraction, Wire Sizing and Drift Velocity (15 marks)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

Given. FCC copper, lattice parameter a = 3.6151 Å, one valence electron per atom; measured conductivity σ = 5.98×105 (Ω·cm)-1; electron mobility μn = 70 cm²/V·s; wire under J = 50,000 A/cm², V = 1000 V, R = 5 Ω.

Find. (a) The percentage of valence electrons actually carrying current; (b) the wire length; (c) the wire diameter; (d) the electron drift velocity.

Approach. Get the theoretical maximum free-electron density from the FCC unit cell (4 atoms/cell, 1 valence electron each), get the actual carrier density from the measured conductivity via σ = nqμ, then use Ohm's law and the resistivity form of R to size the wire, and finally get drift velocity from the current density.

  1. Theoretical valence-electron density from the FCC cell. An FCC cell holds 4 atoms, each contributing 1 valence electron: $$V_{cell}=a^3=(3.6151\times10^{-8}\ \text{cm})^3=4.725\times10^{-23}\ \text{cm}^3$$ $$n_{total}=\dfrac{4\ \text{electrons}}{V_{cell}}=8.466\times10^{22}\ \text{cm}^{-3}$$
  2. Actual carrier density from the measured conductivity. Using the Drude relation σ = nqμ: $$n_{actual}=\dfrac{\sigma}{q\mu_n}=\dfrac{5.98\times10^{5}}{(1.6\times10^{-19})(70)}=5.339\times10^{22}\ \text{cm}^{-3}$$ $$\%\ carrying=\dfrac{n_{actual}}{n_{total}}\times100=\boxed{63.1\%}$$
  3. Wire length (part b). The applied current follows Ohm's law, and the cross-section follows from the stated current density: $$I=\dfrac{V}{R}=\dfrac{1000}{5}=200\ \text{A},\qquad A=\dfrac{I}{J}=\dfrac{200}{50{,}000}=4.0\times10^{-3}\ \text{cm}^2$$ The resistivity is ρ = 1/σ = 1.672×10-6 Ω·cm, so from R = ρL/A, $$L=\dfrac{RA}{\rho}=\dfrac{(5)(4.0\times10^{-3})}{1.672\times10^{-6}}=11{,}960\ \text{cm}=\boxed{119.6\ \text{m}}$$
  4. Wire diameter (part c). From the same cross-sectional area, treating the wire as circular: $$d=\sqrt{\dfrac{4A}{\pi}}=\sqrt{\dfrac{4(4.0\times10^{-3})}{\pi}}=0.0714\ \text{cm}=\boxed{0.714\ \text{mm}}$$
  5. Drift velocity (part d), by two independent routes. Directly from J = nqvd: $$v_d=\dfrac{J}{n_{actual}\,q}=\dfrac{50{,}000}{(5.339\times10^{22})(1.6\times10^{-19})}=\boxed{5.85\ \text{cm/s}}$$ As a check, the field along the wire is E = V/L = 1000/11,960 = 0.0836 V/cm, and vd = μnE = (70)(0.0836) = 5.85 cm/s — the two routes agree exactly because nactual and μn were tied together through σ = nactualqμn in Step 2.
Final results — Question 2
QuantityValue
(a) Fraction of valence electrons conducting63.1%
(b) Wire length119.6 m
(c) Wire diameter0.714 mm
(d) Drift velocity5.85 cm/s