21-Mat-B10 Properties and Processing of Micro- and Nanomaterials · May 2013
Question 2 of 6: Conduction in Copper — Carrier Fraction, Wire Sizing and Drift Velocity
Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
Notes on this paper
National Exams — 10-Met-B10, Advanced Electronic Materials — May 2013, 3 hours. Six questions; Question 6 (40 marks) is mandatory and any 4 of the remaining 5 questions (15 marks each) complete the paper. All six are answered below.
Reference texts: S.O. Kasap, Principles of Electronic Materials and Devices; W.D. Callister, Materials Science and Engineering: An Introduction.
Two points matter: Question 4 prints the GaAs carrier density per m³ (not per cm³), which sets the conductivity scale; and the formula sheet prints Planck's constant as h = 4.375×10-15 eV·s, which is not the physical value (4.136×10-15 eV·s) — the standard value is used in Question 5.1 and the result with the printed value is also given.
Question 2: Conduction in Copper — Carrier Fraction, Wire Sizing and Drift Velocity (15 marks)
Given. FCC copper, lattice parameter a = 3.6151 Å, one valence electron per atom; measured conductivity σ = 5.98×105 (Ω·cm)-1; electron mobility μn = 70 cm²/V·s; wire under J = 50,000 A/cm², V = 1000 V, R = 5 Ω.
Find. (a) The percentage of valence electrons actually carrying current; (b) the wire length; (c) the wire diameter; (d) the electron drift velocity.
Approach. Get the theoretical maximum free-electron density from the FCC unit cell (4 atoms/cell, 1 valence electron each), get the actual carrier density from the measured conductivity via σ = nqμ, then use Ohm's law and the resistivity form of R to size the wire, and finally get drift velocity from the current density.
Theoretical valence-electron density from the FCC cell. An FCC cell holds 4 atoms, each contributing 1 valence electron:
$$V_{cell}=a^3=(3.6151\times10^{-8}\ \text{cm})^3=4.725\times10^{-23}\ \text{cm}^3$$
$$n_{total}=\dfrac{4\ \text{electrons}}{V_{cell}}=8.466\times10^{22}\ \text{cm}^{-3}$$
Actual carrier density from the measured conductivity. Using the Drude relation σ = nqμ:
$$n_{actual}=\dfrac{\sigma}{q\mu_n}=\dfrac{5.98\times10^{5}}{(1.6\times10^{-19})(70)}=5.339\times10^{22}\ \text{cm}^{-3}$$
$$\%\ carrying=\dfrac{n_{actual}}{n_{total}}\times100=\boxed{63.1\%}$$
Wire length (part b). The applied current follows Ohm's law, and the cross-section follows from the stated current density:
$$I=\dfrac{V}{R}=\dfrac{1000}{5}=200\ \text{A},\qquad A=\dfrac{I}{J}=\dfrac{200}{50{,}000}=4.0\times10^{-3}\ \text{cm}^2$$
The resistivity is ρ = 1/σ = 1.672×10-6 Ω·cm, so from R = ρL/A,
$$L=\dfrac{RA}{\rho}=\dfrac{(5)(4.0\times10^{-3})}{1.672\times10^{-6}}=11{,}960\ \text{cm}=\boxed{119.6\ \text{m}}$$
Wire diameter (part c). From the same cross-sectional area, treating the wire as circular:
$$d=\sqrt{\dfrac{4A}{\pi}}=\sqrt{\dfrac{4(4.0\times10^{-3})}{\pi}}=0.0714\ \text{cm}=\boxed{0.714\ \text{mm}}$$
Drift velocity (part d), by two independent routes. Directly from J = nqvd:
$$v_d=\dfrac{J}{n_{actual}\,q}=\dfrac{50{,}000}{(5.339\times10^{22})(1.6\times10^{-19})}=\boxed{5.85\ \text{cm/s}}$$
As a check, the field along the wire is E = V/L = 1000/11,960 = 0.0836 V/cm, and vd = μnE = (70)(0.0836) = 5.85 cm/s — the two routes agree exactly because nactual and μn were tied together through σ = nactualqμn in Step 2.