23-Chem-A5 Chemical Plant Design and Economics · May 2017
Question 5 of 6: Safety Considerations in Chemical Industries
Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
Notes on this paper
Closed-book exam, 3 hours; one aid sheet permitted. Six questions of equal value (20 marks each); five constitute a complete paper — full solutions to all six are given here. Questions 1 and 2 are quantitative (plant material balance and discounted-cash-flow return); Questions 3–6 are design-practice list/essay questions.
Reference texts: M.S. Peters, K.D. Timmerhaus & R.E. West, Plant Design and Economics for Chemical Engineers (5th ed., McGraw-Hill) — the exam's named primary text (process design development Ch. 2, general design considerations: plant location, safety, materials Ch. 3, interest and profitability Ch. 7–10, materials-transfer/pumps Ch. 14); R.H. Perry & D.W. Green, Perry's Chemical Engineers' Handbook (9th ed.) — pump types and selection (Sec. 10), pyrolysis kinetics data; O. Levenspiel, Chemical Reaction Engineering (3rd ed.) — first-order plug-flow space-time behind the reactor sizing in Question 1; supporting Canadian practice from CCOHS and the CSA Z767 / provincial OH&S process-safety-management framework for Question 5.
Question 5: Safety Considerations in Chemical Industries (20 marks)
Given / Find. A process-safety question. Each of the five hazard categories is answered with the key design and operating considerations that reduce or control that hazard, consistent with Canadian OH&S and process-safety-management practice.
(a) Building and process equipment
Adequate spacing/segregation of units; fire-resistant, non-combustible construction.
Open (well-ventilated) structures to prevent vapour accumulation; explosion venting/blast walls.
Multiple, clearly marked exits and escape routes; safe layout of aisles and access.
Pressure vessels and piping designed to code (ASME/CSA) with relief devices; guarded/shielded hot and high-pressure equipment.
(b) Fire prevention and control
Eliminate ignition sources near flammables; control flammable-vapour release (bonding, purging, inerting).
Fixed and portable fire-fighting: hydrants, sprinklers/deluge, foam, CO2/dry-chemical suited to the fuel.
Fire and gas detection with alarms; emergency isolation and depressuring/blowdown systems.
Firewater supply and containment (dikes/bunds); trained fire brigade and emergency plan.
(c) Mechanical hazards
Guards on rotating and moving machinery (couplings, belts, shafts); lock-out/tag-out for maintenance.
Protection from falls, falling objects, and moving vehicles; safe access, platforms, and handrails.
Relief of stored mechanical/pressure energy before servicing; proper lifting and materials handling.
Noise and vibration control; personal protective equipment.
(d) Electrical hazards
Proper grounding and bonding of equipment; protection against shock and static discharge.
Explosion-proof / intrinsically-safe electrical equipment in classified (hazardous) areas.
Overcurrent protection, insulation, and guarding of live parts; lock-out of electrical supplies for work.
Emergency and standby power for critical safety systems; compliance with the electrical code.
(e) Chemical hazards
Knowledge of toxicity, flammability, reactivity, and exposure limits (SDS) for every chemical.
Containment of toxic/corrosive materials; ventilation, scrubbing, and gas detection for leaks.
Prevention of runaway/incompatible-chemical reactions; adequate cooling, relief, and segregated storage.
Personal protection, safe handling and disposal procedures, and emergency showers/eyewash and first aid.