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18-Env-B5 Industrial & Hazardous Waste Management · May 2018

Question 2 of 14: Four Characteristics That Make a Waste Hazardous

Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)

Notes on this paper

Reference texts: LaGrega, Buckingham & Evans, Hazardous Waste Management, 2nd ed.; Nemerow & Dasgupta, Industrial and Hazardous Waste Treatment, 2nd ed.; Metcalf & Eddy, Wastewater Engineering: Treatment and Resource Recovery, 5th ed.; Davis & Cornwell, Introduction to Environmental Engineering, 6th ed.; Cooper & Alley, Air Pollution Control: A Design Approach; CCME, Guidelines for the Management of Biomedical Waste in Canada (1992); Ontario Environmental Protection Act, R.S.O. 1990, c. E.19 and O. Reg. 347 (Waste Management – General); Transportation of Dangerous Goods Act, 1992 (Canada) and Regulations; Canadian Environmental Protection Act (CEPA), 1999.

Question 2: Four Characteristics That Make a Waste Hazardous (4 marks)

Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.

Regulatory schemes on both sides of the border (US RCRA, and the characteristic-waste criteria adopted in Canadian frameworks such as Ontario's O. Reg. 347) classify a waste as hazardous "by characteristic" if it exhibits any one of four measurable properties:

  1. Ignitability. A liquid with a flash point below $60^{\circ}\text{C}$ ($140^{\circ}\text{F}$), a non-liquid capable of spontaneous, sustained combustion under normal handling, an ignitable compressed gas, or an oxidizer.
  2. Corrosivity. An aqueous waste with pH $\le 2$ or pH $\ge 12.5$, or a liquid that corrodes steel at a specified rate — capable of destroying living tissue or corroding containment/transport equipment on contact.
  3. Reactivity. Waste that is unstable and readily undergoes violent change, reacts violently or generates toxic gas with water, is capable of detonation, or is a forbidden explosive, cyanide- or sulfide-bearing waste that liberates toxic gas at low pH.
  4. Toxicity. Waste that, when subjected to a standardized leaching test (e.g. the Toxicity Characteristic Leaching Procedure, TCLP), releases one or more regulated contaminants (heavy metals, specific organics) into the leachate above a stated concentration threshold — a proxy for the waste's potential to contaminate groundwater once landfilled.

These four tests are deliberately cheap, standardized laboratory procedures rather than full risk assessments, so a waste can be screened and classified in days rather than months; a generator only needs a positive result on ONE of the four to trigger the full cradle-to-grave hazardous-waste management obligations (manifesting, licensed transport, approved disposal). Question 3 works through exactly this logic for two specific wastes, applying the ignitability and corrosivity thresholds directly to measured properties.