21-Mat-A2 Materials Transport Phenomena · December 2013
Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
National Exams — December 2013 — Met-A2, Metallurgical Rate Phenomena. Three-hour, closed-book exam using an approved (Casio or Sharp) calculator, one double-sided aid sheet permitted; candidates were told to state any interpretive assumptions. Candidates answer Question 1 plus any four of Questions 2–9 — all nine are solved below for completeness. All questions are of equal value (20 marks each, five questions = 100%).
Reference texts: Geankoplis, C. J., Transport Processes and Separation Process Principles — mass/heat/momentum transfer fundamentals (Fick's/Newton's/Fourier's laws, boundary-layer correlations); Szekely, J. & Themelis, N. J., Rate Phenomena in Process Metallurgy — gas-halo diffusion, ladle/tundish fluid flow, wire injection; Turkdogan, E. T., Fundamentals of Steelmaking — BOF/EAF heat and mass balances; Callister, W. D., Materials Science and Engineering — TTT/CCT diagrams and phase transformations; Incropera, F. P. & DeWitt, D. P., Fundamentals of Heat and Mass Transfer — liquid-metal (low-Pr) convection correlations.
Question text not reproduced: the examination questions are © Engineers and Geoscientists BC. Open the official past paper (linked at the top of this page) to read the question, then follow the worked solution below.
Given. $d=0.01$ m, $T_{bath}=1600\,{}^{\circ}\text{C}$, $T_{m,Al}=660\,{}^{\circ}\text{C}$ (superheat driving force $\Delta T=940$ K), target depth $=2.7$ m, feed temperature taken as ambient ($25\,{}^{\circ}\text{C}$). $\rho_{Al}=2700$, $C_{p,Al,s}=902$ J/kg K, $L_{Al}=387{,}000$ J/kg. Liquid steel: $k=28$ W/m K, $\mu=7\times10^{-3}$ Pa s, $C_p=750$ J/kg K, $\rho=7000$ kg/m³.
Find. The wire feed velocity $v$ that lets the wire just finish melting at 2.7 m depth, by (i) the given $Nu_L$ correlation and (ii) the Mucciardi & Guthrie empirical correlation; compare.
Approach. $Nu_L=1.12\,Re_L^{0.5}Pr^{0.5}$ is the low-Prandtl (liquid-metal) flat-plate correlation Question 4 derived (its length-averaged form), so $L$ here is the wire’s submerged travel distance (depth), not its diameter — the boundary layer develops along the wire’s path exactly as it does along Q4’s plate. The wire’s energy requirement (sensible heat to melting point + latent heat) must be supplied by convection from the bath over the transit time $\tau=$depth$/v$; setting the two equal, with $h$ itself a function of $v$ through $Re_L$, gives an implicit (numerically converged) expression for $v$.
The two independent estimates (10.5 m/s from first-principles convection theory, 13.2 m/s from the empirical correlation) agree to within about 25% — a reasonable match given the very different derivations. The theoretical $Nu_L$ route idealises the wire as a smooth, static-relative-to-bath flat-plate analogue with uniform properties and neglects the plant-scale turbulence of the “strong-stir” ladle station, local convection currents, any oxide film on the wire, and the fact that melting itself changes the effective wire diameter along its length; the empirical correlation, fitted to real plant/lab wire-injection trials, implicitly captures these effects and is generally the more trustworthy number for design, with the theoretical route serving as an independent order-of-magnitude check.
| Quantity | Value |
|---|---|
| Energy to melt 1 m of wire | 2.035 × 10⁵ J/m |
| Liquid-steel Prandtl number | 0.1875 |
| Wire velocity (Nu₃ theory) | ≈ 10.5 m/s |
| Wire velocity (Mucciardi–Guthrie correlation) | ≈ 13.2 m/s |