25-Nav-A1 Fundamentals of Naval Architecture · May-98-Mar-A1 2017
Question 4 of 8: Ammonia Refrigeration Cycle
Nivaar worked solution (AI-drafted; not reviewed by a licensed engineer)
Notes on this paper
National Examinations, May 2017 — 98-Mar-A1 Applied Thermodynamics and Heat Transfer, 3 hours, open book (Part A: Thermodynamics, Part B: Heat Transfer; 5 of 8 questions required, all 8 answered below for full study coverage).
Reference texts: Cengel & Boles, Thermodynamics: An Engineering Approach; Sonntag, Borgnakke & Van Wylen, Fundamentals of Thermodynamics; Incropera & DeWitt, Fundamentals of Heat and Mass Transfer.
It is solved as the thermodynamics/heat-transfer exam it actually is.
Approach. Read $h_f$ at 27°C for the sub-cooled/near-saturated liquid entering the throttle (standard approximation $h\approx h_f@T$); throttling is isenthalpic, so this fixes $h$ at the evaporator inlet; evaluate quality against saturation properties at 250 kPa; find the evaporator-exit enthalpy from the (superheated) state at -10°C; close the cycle with an energy balance on the evaporator and the definition of COP.
Enthalpy before the throttle (interpolated saturated-liquid table, 26°C/28°C).
$$h_3=h_f@27\,{}^{\circ}\text{C}\approx\tfrac12(303.6+313.2)=308.4\text{ kJ/kg}$$
Saturation state at 250 kPa (interpolated between -14°C/246.51 kPa and -12°C/267.95 kPa). $T_{sat}\approx-13.7\,{}^{\circ}\text{C}$, $h_f\approx118.4\text{ kJ/kg}$, $h_g\approx1427.4\text{ kJ/kg}$, $h_{fg}\approx1309.0\text{ kJ/kg}$.
Quality after throttling ($h_4=h_3$, isenthalpic).
$$x_4=\dfrac{h_4-h_f}{h_{fg}}=\dfrac{308.4-118.4}{1309.0}=\boxed{0.145\ (14.5\%)}$$
Evaporator-exit enthalpy. Exit at -10°C is $\approx3.7\,{}^{\circ}\text{C}$ of superheat above $T_{sat}(250\text{ kPa})=-13.7\,{}^{\circ}\text{C}$. Using an ammonia-vapour $c_p\approx2.6\text{ kJ/kg}\!\cdot\!\text{K}$ near this state, $h_1\approx h_g+c_p\Delta T_{sh}=1427.4+2.6(3.7)=1437.0\text{ kJ/kg}$.
Coefficient of performance.
$$\text{COP}=\dfrac{\dot Q_{evap}}{\dot W_{comp}}=\dfrac{7.90}{2.12}=\boxed{3.73}$$
Question 4 — final results
Quantity
Value
Quality leaving throttle valve
$x_4 = 0.145\ (14.5\%)$
Evaporator heat-absorption rate
$\dot Q_{evap} = 7.90\text{ kW}$
Coefficient of performance
$\text{COP} = 3.73$
This affects only steps 4–6 (evaporator duty and COP); the throttling quality in step 3 is unaffected and uses only the saturated-liquid/saturated-vapour tables transcribed in full.